Engineering the coordination environment enables molybdenum single-atom catalyst for efficient oxygen reduction reaction
文献类型：期刊论文
| 作者 | Wang, Changlai1,4; Wang, Dongdong2; Liu, Shuai1; Jiang, Peng1; Lin, Zhiyu1; Xu, Pengping1; Yang, Kang1; Lu, Jian1; Tong, Huigang1; Hu, Lin3 |
| 刊名 | JOURNAL OF CATALYSIS
 |
| 出版日期 | 2020-09-01 |
| 卷号 | 389 |
| ISSN号 | 0021-9517 |
| 关键词 | Single-atom catalyst D-band center Reaction barrier DFT calculations Zn-air battery |
| DOI | 10.1016/j.jcat.2020.05.034 |
| 通讯作者 | Zhang, Wenjun(apwjzh@cityu.edu.hk) ; Chen, Qianwang(cqw@ustc.edu.cn) |
| 英文摘要 | With a half filled d-electron shell, molybdenum (Mo) plays an important role as catalysts in the petrochemical industry. However, Mo is generally regarded as not catalytically active for oxygen reduction reaction (ORR) compared with other transition metals such as Fe and Co. Inspired by molybdoenzymes, herein, we successfully endow Mo single-atom catalyst with highly ORR catalytic activity though engineering the coordination environment. This unique Mo single-atom catalyst consists of oxygen and nitrogen dual-component coordinated central Mo atom anchored on porous carbon (Mo-O/N-C), showing prominent ORR catalytic performance compared to the state-of-the-art Pt/C under alkaline condition. The extraordinary performance of Mo-O/N-C electrocatalyst is also demonstrated in Zn-air batteries as an air cathode. Density functional theory (DFT) calculations reveal the oxygen and nitrogen dual-component coordination could tailor the d-band center of Mo, subsequently optimizing its binding capability with reaction intermediates (O*, OH* and OOH*), hence accelerating overall ORR process. This work not only provides an efficient and commercially competitive ORR catalyst, but advancing further development of other electrocatalysts through engineering the coordination environment. (C) 2020 Published by Elsevier Inc. |
| WOS关键词 | CARBON ; PLATINUM ; ALLOY ; ELECTROCATALYSTS ; GRAPHENE ; METAL ; OXIDE |
| 资助项目 | Hong Kong Scholars Program[XJ2019022] ; National Natural Science Foundation[51772283] ; National Natural Science Foundation[21972145] ; National Natural Science Foundation[51872249] ; Hefei Science Center CAS[2016HSC-IU011] ; National Key R&D Program of China[2016YFA0401801] ; Fundamental Research Funds for the Central Universities[WK2060140021] ; Key Lab of Photovoltaic and Energy Conservation Materials of Chinese Academy of Sciences[PECL2019QN004] ; General Research Fund[GRF CityU 11307619] |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| WOS记录号 | WOS:000566793900016 |
| 资助机构 | Hong Kong Scholars Program ; National Natural Science Foundation ; Hefei Science Center CAS ; National Key R&D Program of China ; Fundamental Research Funds for the Central Universities ; Key Lab of Photovoltaic and Energy Conservation Materials of Chinese Academy of Sciences ; General Research Fund |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/104015]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Zhang, Wenjun; Chen, Qianwang |
| 作者单位 | 1.Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China 2.Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, 21 Nanyang Link, Singapore 637371, Singapore 3.Chinese Acad Sci, Hefei Inst Phys Sci, Anhui Key Lab Condensed Mater Phys Extreme Condit, High Magnet Field Lab, Hefei 230031, Anhui, Peoples R China 4.City Univ Hong Kong, Ctr Super Diamond & Adv Films COSDAF, Dept Mat Sci & Engn, Kowloon, Tat Chee Ave, Hong Kong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Changlai,Wang, Dongdong,Liu, Shuai,et al. Engineering the coordination environment enables molybdenum single-atom catalyst for efficient oxygen reduction reaction[J]. JOURNAL OF CATALYSIS,2020,389. |
| APA | Wang, Changlai.,Wang, Dongdong.,Liu, Shuai.,Jiang, Peng.,Lin, Zhiyu.,...&Chen, Qianwang.(2020).Engineering the coordination environment enables molybdenum single-atom catalyst for efficient oxygen reduction reaction.JOURNAL OF CATALYSIS,389. |
| MLA | Wang, Changlai,et al."Engineering the coordination environment enables molybdenum single-atom catalyst for efficient oxygen reduction reaction".JOURNAL OF CATALYSIS 389(2020). |
入库方式： OAI收割
来源：合肥物质科学研究院
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。