Energetic Metal-Organic Frameworks Derived Highly Nitrogen-Doped Porous Carbon for Superior Potassium Storage
文献类型：期刊论文
| 作者 | Tong, Huigang1; Wang, Changlai1,2; Lu, Jian1; Chen, Shi1; Yang, Kang1; Huang, Minxue1; Yuan, Qing1; Chen, Qianwang1,3
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| 刊名 | SMALL
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| 出版日期 | 2020-10-04 |
| 关键词 | energetic metal-organic frameworks N-doped porous carbon frameworks potassium-ion batteries pyridinic N pyrrolic N |
| ISSN号 | 1613-6810 |
| DOI | 10.1002/smll.202002771 |
| 通讯作者 | Chen, Qianwang(cqw@ustc.edu.cn) |
| 英文摘要 | The carbonaceous materials with low cost and high safety have been considered as promising anodes for potassium-ion batteries (PIBs). However, it is still a challenge to design a carbonaceous material with long cycle life and high rate performance due to the poor K(+)reaction kinetics. Herein, this article reports a N-doped porous carbon framework (NPCF) with a high nitrogen content of 13.57 at% within high doping level of the pyrrolic N and pyridinic N, which exhibits a high reversible capacity of 327 mA h g(-1)over 100 cycles at a current density of 100 mA g(-1), excellent rate capability (144 and 105 mA h g(-1)at 10 and 20 A g(-1), respectively) and great cyclability of 258.9 mA h g(-1)after 2000 cycles at 1 A g(-1). Such a high rate performance and excellent cycling stability anode material is seldom reported in PIBs. Density functional theory (DFT) calculations reveal that the pyrrolic and pyridinic N-doping are helpful to enhance the K adsorption ability, thereby increasing the specific capacity. |
| WOS关键词 | HOLLOW CARBON ; BATTERY ; FABRICATION ; ANODE ; FILM |
| 资助项目 | National Natural Science Foundation (NSFC)[51772283] ; National Key R&D 229 Program of China[2016YFA0401801] ; Hong Kong Scholars Program[XJ2019022] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000574858800001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation (NSFC) ; National Key R&D 229 Program of China ; Hong Kong Scholars Program |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/104296]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Chen, Qianwang |
| 作者单位 | 1.Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China 2.City Univ Hong Kong, Dept Mat Sci & Engn, Ctr Super Diamond & Adv Films COSDAF, Kowloon, Tat Chee Ave, Hong Kong, Peoples R China 3.Chinese Acad Sci, Hefei Inst Phys Sci, High Field Magnet Lab, Anhui Key Lab Condensed Mater Phys Extreme Condit, Hefei 230031, Anhui, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tong, Huigang,Wang, Changlai,Lu, Jian,et al. Energetic Metal-Organic Frameworks Derived Highly Nitrogen-Doped Porous Carbon for Superior Potassium Storage[J]. SMALL,2020. |
| APA | Tong, Huigang.,Wang, Changlai.,Lu, Jian.,Chen, Shi.,Yang, Kang.,...&Chen, Qianwang.(2020).Energetic Metal-Organic Frameworks Derived Highly Nitrogen-Doped Porous Carbon for Superior Potassium Storage.SMALL. |
| MLA | Tong, Huigang,et al."Energetic Metal-Organic Frameworks Derived Highly Nitrogen-Doped Porous Carbon for Superior Potassium Storage".SMALL (2020). |
入库方式： OAI收割
来源：合肥物质科学研究院
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