Fe-Co Alloyed Nanoparticles Catalyzing Efficient Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol in Water
文献类型：期刊论文
| 作者 | Lv, Yang1; Han, Miaomiao1; Gong, Wanbing1; Wang, Dongdong1; Chen, Chun1 ; Wang, Guozhong1; Zhang, Haimin1; Zhao, Huijun1,2
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| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2020-10-23 |
| 关键词 | cinnamaldehyde Fe-Co nanoalloys H2O solvent metal– organic frameworks selective hydrogenation |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.202009913 |
| 通讯作者 | Gong, Wanbing(wbgong@issp.ac.cn) ; Zhao, Huijun(h.zhao@griffith.edu.au) |
| 英文摘要 | Selective hydrogenation of C=O against the conjugated C=C in cinnamaldehyde (CAL) is indispensable to produce cinnamyl alcohol (COL). Nonetheless, it is challenged by the low selectivity and the need to use organic solvents. Herein, for the first time, we report the use of Fe-Co alloy nanoparticles (NPs) on N-doped carbon support as a selective hydrogenation catalyst to efficiently convert CAL to COL. The resultant catalyst with the optimized Fe/Co ratio of 0.5 can achieve an exceptional COL selectivity of 91.7 % at a CAL conversion of 95.1 % in pure water medium under mild reaction conditions, ranking it the best performed catalyst reported to date. The experimental results confirm that the COL selectivity and CAL conversion efficiency are, respectively promoted by the presence of Fe and Co, while the synergism of the alloyed Fe-Co is the key to concurrently achieve high COL selectivity and CAL conversion efficiency. |
| WOS关键词 | METAL-ORGANIC FRAMEWORKS ; SELECTIVE HYDROGENATION ; CATALYSTS |
| 资助项目 | Natural Science Foundation of China[51871209] ; Natural Science Foundation of China[51902311] ; Postdoctoral Science Foundation of China[2019M652223] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000582370700001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | Natural Science Foundation of China ; Postdoctoral Science Foundation of China |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/104621]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Gong, Wanbing; Zhao, Huijun |
| 作者单位 | 1.Chinese Acad Sci, Anhui Key Lab Nanomat & Nanotechnol, CAS Ctr Excellence Nanosci,Inst Solid State Phys, Key Lab Mat Phys,Ctr Environm & Energy Nanomat, Hefei 230031, Peoples R China 2.Griffith Univ, Ctr Clean Environm & Energy, Gold Coast Campus, Southport, Qld 4222, Australia |
| 推荐引用方式 GB/T 7714 | Lv, Yang,Han, Miaomiao,Gong, Wanbing,et al. Fe-Co Alloyed Nanoparticles Catalyzing Efficient Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol in Water[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2020. |
| APA | Lv, Yang.,Han, Miaomiao.,Gong, Wanbing.,Wang, Dongdong.,Chen, Chun.,...&Zhao, Huijun.(2020).Fe-Co Alloyed Nanoparticles Catalyzing Efficient Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol in Water.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. |
| MLA | Lv, Yang,et al."Fe-Co Alloyed Nanoparticles Catalyzing Efficient Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol in Water".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020). |
入库方式： OAI收割
来源：合肥物质科学研究院
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