Ultrathin iron-cobalt oxide nanosheets with enhanced H2O2 activation performance for efficient degradation of tetracycline
文献类型：期刊论文
| 作者 | Nie, Mingxing3,4; Li, Yulian3,4; Li, Lianxiang1; He, Junyong3; Hong, Peidong3,4; Zhang, Kaisheng3; Cai, Xinli2; Kong, Lingtao3 ; Liu, Jinhuai3
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| 刊名 | APPLIED SURFACE SCIENCE
 |
| 出版日期 | 2021 |
| 卷号 | 535 |
| ISSN号 | 0169-4332 |
| 关键词 | Tetracycline Fenton process Mechanism Pathways CoFe-ONSs |
| DOI | 10.1016/j.apsusc.2020.147655 |
| 通讯作者 | Li, Lianxiang(lianxiang.0810@163.com) ; Cai, Xinli(ahcxl@163.com) ; Kong, Lingtao(ltkong@iim.ac.cn) |
| 英文摘要 | Ultrathin iron-cobalt oxide nanosheets (CoFe-ONSs) synthesized via a facile one-step routine by using NaBH4 as the reductant were used for H2O2 activation and tetracycline (TC) elimination. The CoFe-ONSs realized 83.5% removal of TC under the neutral conditions after 50 min with 0.3 g/L catalyst, 20 mM H2O2 and 50 mg/L TC. The effects of catalyst dosage, H2O2 concentration, initial pH, temperature, initial TC concentration, anions and water sources on TC degradation were studied. Hydroxyl ((OH)-O-center dot) radicals were the main active species in the entire reaction, which was demonstrated by quenching experiments, fluorescence detection and the electron paramagnetic resonance (EPR) technology. Additionally, the redox cycles of Fe-II/Fe-III and Co-II/Co-III were participated in (OH)-O-center dot generation. What's more, the plausible degradation pathways were put forward followed with detected intermediates. The CoFe-ONSs displayed negligible iron ions leaching and held high TC elimination performance even after five trials. Therefore, the CoFe-ONSs may expand the heterogeneous Fenton-like catalysts family and display great potential in eliminating antibiotic contaminants from wastewater. |
| WOS关键词 | ANTIBIOTIC-RESISTANT BACTERIA ; FENTON-LIKE CATALYST ; WASTE-WATER ; BISPHENOL-A ; HYDROTHERMAL SYNTHESIS ; OXIDATION PROCESSES ; ORGANIC-COMPOUNDS ; AZO-DYE ; REMOVAL ; PEROXYMONOSULFATE |
| 资助项目 | State Key Research Development Program of China[2019YFC0408500] ; Natural Science Foundation of China[2196182] ; Natural Science Foundation of China[61873253] ; Science and Technology Major Projects of Anhui Province[18030801104] ; Science and Technology Major Projects of Anhui Province[18030801106] ; China Postdoctoral Science Foundation[2019M652227] |
| WOS研究方向 | Chemistry ; Materials Science ; Physics |
| 语种 | 英语 |
| 出版者 | ELSEVIER |
| WOS记录号 | WOS:000582373900019 |
| 资助机构 | State Key Research Development Program of China ; Natural Science Foundation of China ; Science and Technology Major Projects of Anhui Province ; China Postdoctoral Science Foundation |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/104832]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Li, Lianxiang; Cai, Xinli; Kong, Lingtao |
| 作者单位 | 1.Minist Water Resources, China Irrigat & Drainage Dev Ctr, Rural Drinking Water Safety Ctr, Beijing 100054, Peoples R China 2.Anhui Jianzhu Univ, Coll Environm & Energy Engn, Hefei 230601, Peoples R China 3.Chinese Acad Sci, Inst Intelligent Machines, Nanomat & Environm Detect Lab, Hefei 230031, Peoples R China 4.Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China |
| 推荐引用方式 GB/T 7714 | Nie, Mingxing,Li, Yulian,Li, Lianxiang,et al. Ultrathin iron-cobalt oxide nanosheets with enhanced H2O2 activation performance for efficient degradation of tetracycline[J]. APPLIED SURFACE SCIENCE,2021,535. |
| APA | Nie, Mingxing.,Li, Yulian.,Li, Lianxiang.,He, Junyong.,Hong, Peidong.,...&Liu, Jinhuai.(2021).Ultrathin iron-cobalt oxide nanosheets with enhanced H2O2 activation performance for efficient degradation of tetracycline.APPLIED SURFACE SCIENCE,535. |
| MLA | Nie, Mingxing,et al."Ultrathin iron-cobalt oxide nanosheets with enhanced H2O2 activation performance for efficient degradation of tetracycline".APPLIED SURFACE SCIENCE 535(2021). |
入库方式： OAI收割
来源：合肥物质科学研究院
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