Development of a portable cavity ring down spectroscopy instrument for simultaneous, in situ measurement of NO3 and N2O5
文献类型:期刊论文
作者 | Li, Zhiyan1,4; Hu, Renzhi1![]() ![]() ![]() ![]() |
刊名 | OPTICS EXPRESS
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出版日期 | 2018-05-14 |
卷号 | 26期号:10页码:A433-A449 |
ISSN号 | 1094-4087 |
DOI | 10.1364/OE.26.00A433 |
英文摘要 | An inexpensive, compact instrument for sensitive measurement of nocturnal nitrogen oxides NO3 and N2O5 in ambient air at high time resolution has been described. The instrument measures NO3 and N(2)O(5 )which is converted into the NO3 radical through thermal decomposition by optical extinction using a diode laser at 662.08 mn in two separate detection channels. The minimum detection limits (1 sigma) for the NO3 radical and N2O5 are estimated to be 2.3 pptv and 3.1 pptv in an average time of 2.5 s, with the accessible effective absorption path length generally exceeding 30 km, which is sufficient for quantifying NO3 radical and N2O5 concentrations under moderately polluted conditions. The total uncertainties of the NO3 and N2O5 measurements are 8% and 15% respectively. which are mainly dominated by the uncertainty of NO3 across section calculated for 353 K in this system. In addition, the dependence of the instnunent's sensitivity and accuracy on a variety of conditions was presented in winter of 2016 and in summer of 2017 during two China-UK joint campaigns. Distinct N(2)O(5)vertical profiles were observed at night in winter. The equilibrium among observed NO2 , NO3 and N(2)O(5)based on the equilibrium constants during summer time also provides confirmation of the measurement accuracy of the instnunent. (C) 2018 Optical Society of America under the terms of the OSA Open Access Publishing Agreement |
WOS关键词 | ENHANCED ABSORPTION SPECTROMETER ; IONIZATION MASS-SPECTROMETRY ; VOLATILE ORGANIC-COMPOUNDS ; NOCTURNAL NITROGEN-OXIDES ; DOWN SPECTROSCOPY ; TEMPERATURE-DEPENDENCE ; DINITROGEN PENTOXIDE ; INDUCED FLUORESCENCE ; NIGHTTIME CHEMISTRY ; RADICAL CHEMISTRY |
资助项目 | National Natural Science Foundation of China[41530644] ; National Natural Science Foundation of China[41571130023] ; National Natural Science Foundation of China[61575206] ; National Natural Science Foundation of China[91644107] ; National Key Research and Development Program of China[2017YFC0209401] ; National Key Research and Development Program of China[2017YFC0209403] |
WOS研究方向 | Optics |
语种 | 英语 |
WOS记录号 | WOS:000432457600006 |
出版者 | OPTICAL SOC AMER |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/36728] ![]() |
专题 | 合肥物质科学研究院_中科院安徽光学精密机械研究所 |
通讯作者 | Hu, Renzhi |
作者单位 | 1.Chinese Acad Sci, Anhui Inst Opt & Fine Mech, Key Lab Environm Opt & Technol, Hefei 230031, Anhui, Peoples R China 2.Anhui Univ Sci & Technol, Sch Elect & Informat Engn, Huainan 232001, Anhui, Peoples R China 3.Chinese Acad Sci, Inst Urban Environm, CAS Ctr Excellence Reg Atmospher Environm, Xiamen 361000, Fujian, Peoples R China 4.Univ Sci & Technol China, Grad Sch, Sci Isl Branch, Hefei 230026, Anhui, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Zhiyan,Hu, Renzhi,Xie, Pinhua,et al. Development of a portable cavity ring down spectroscopy instrument for simultaneous, in situ measurement of NO3 and N2O5[J]. OPTICS EXPRESS,2018,26(10):A433-A449. |
APA | Li, Zhiyan.,Hu, Renzhi.,Xie, Pinhua.,Chen, Hao.,Wu, Shengyang.,...&Liu, Wenqing.(2018).Development of a portable cavity ring down spectroscopy instrument for simultaneous, in situ measurement of NO3 and N2O5.OPTICS EXPRESS,26(10),A433-A449. |
MLA | Li, Zhiyan,et al."Development of a portable cavity ring down spectroscopy instrument for simultaneous, in situ measurement of NO3 and N2O5".OPTICS EXPRESS 26.10(2018):A433-A449. |
入库方式: OAI收割
来源:合肥物质科学研究院
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