An algorithm for automated fitting of the effective electron temperature from a planar Langmuir probeI-Vtrace taken in a plasma with multiple Maxwellian electron populations is developed through MATLAB coding. The code automatically finds a fitting range suitable for analyzing the temperatures of each of the electron populations. The algorithm is used to analyzeI-Vtraces from both the Institute of Plasma Physics Chinese Academy of Sciences's Diagnostic Test Source device and a similar multi-dipole chamber at the University of Wisconsin-Madison.I-Vtraces reconstructed from the parameters fitted by the algorithm not only agree with the measuredI-Vtrace but also reveal physical properties consistent with those found in previous studies. Cylindrical probe traces are also analyzed with the algorithm and it is shown that the major source of error in such attempts is the disruption of the inflection point due to both decreased signal-to-noise ratio and greater sheath expansion. It is thus recommended to use planar probes with radii much greater than the plasma Debye length when signal-to-noise ratio is poor.