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  4. 中科院安徽光学精密机械研究所
Novel Coalbed Methane (CBM) Origin Analysis and Source Apportionment Method Based on Carbon Isotope Ratio Using Infrared Dual-Wavelength Laser Absorption Spectroscopy

文献类型：期刊论文

作者Zhang, Zhirong3,4; Sun, Pengshuai4; Li, Zhe2,4; Xia, Hua4; Cui, Xiaojuan4; Pang, Tao4; Wu, Bian4; Guo, Qiang4; Shu, Chimin1; Dong, Fengzhong2,3,4
刊名EARTH AND SPACE SCIENCE
出版日期2018-11-01
卷号5期号:11页码:721-735
ISSN号2333-5084
关键词coalbed methane (CBM) origin analysis and source apportionment carbon isotope ratio dual-wavelength laser absorption spectroscopy tunable diode laser absorption spectroscopy (TDLAS) wavelength modulation integrated cavity output spectroscopy isotope ratio mass spectrometer (IRMS)
DOI10.1029/2018EA000437
通讯作者Zhang, Zhirong(zhangzr@aiofm.ac.cn) ; Dong, Fengzhong(fzdong@aiofm.ac.cn)
英文摘要We report the application of an infrared dual-wavelength laser absorption spectroscopy system, which combines tunable diode laser absorption spectroscopy and wavelength modulation integrated cavity output spectroscopy technologies based on two spectroscopic sources operating at 6,029 and 2,310 cm(-1), to simultaneously measure the gas concentrations (CH4 and CO2) and carbon isotopic signatures (C-13 and C-12) in coalbed methane. The Allan variance is used to analyze the optimum mean time (t) and the standard deviation (SD), with t=450s, SD=0.41 parts per thousand for (CH4)-C-13 monitoring and t=70s, SD=0.17 for (CO2)-C-13 monitoring. Furthermore, 47 groups of coalbed methane samples collected from the Huaibei-Qidong coal mine seam are analyzed based on the measured results for carbon isotopes and geophysical geochemistry. The delta(CH4)-C-13 values of the Qidong coal mine fall between -44.57 parts per thousand and -61.57 parts per thousand, and the delta(CO2)-C-13 values fall between -21.65 parts per thousand and -17.06 parts per thousand. The genetic types of methane may be divided into biogenic gas, thermogenic gas, and mixture gas. Carbon dioxide may be derived from coal pyrolysis, and it also has the characteristics of carbon-isotope changes of organic genetic gas. The new approach for analyzing rapid genetic types, methane migration pathways, gas disaster source warning, and coal chemistry studies is expected to be further studied in the future. Plain Language Summary In coal mine research, the measurement of carbon isotopic characteristics and the geochemical method have been found to be some of the most effective methods to identify the genesis, transport process, and source of coalbed methane (CBM). However, the application of carbon isotope measurement to gas outburst and transport in coal mines is still rare. Conventionally, the isotope has been determined by isotope ratio mass spectrometer measurements because of their high sensitivity and high accuracy, but its application range and frequency of sample analysis are severely limited because of its size, complex structure, high time consumption, sample collection, and complex preparation. In this paper, we introduce an infrared dual-wavelength laser absorption spectroscopy system, which combines tunable diode laser absorption spectroscopy and wavelength modulation integrated cavity output spectroscopy technologies based on two spectroscopic sources operating at 6,029 and 2,310cm(-1), to simultaneously measure the gas concentrations (CH4 and CO2) and carbon isotopic signatures (C-13 and C-12) in CBM. Furthermore, 47 groups of CBM samples collected from the Huaibei-Qidong coal mine seam are analyzed based on the measured results for carbon isotopes and geophysical geochemistry. The measurement results show good agreement with reference isotope ratio mass spectrometer measurements, confirming the accuracy of the proposed system.
WOS关键词MODULATION SPECTROSCOPY ; EMISSIONS ; DIOXIDE ; SYSTEM ; WATER
资助项目External Cooperation Program of Chinese Academy of Sciences[GJHZ1726] ; Special Fund for Basic Research on Scientific Instruments of the Chinese Academy of Science[YZ201315] ; National Key Technology Research and Development Program of the Ministry of Science and Technology of China[2014BAC17B03] ; Science and Technology Program of Anhui Province[1604a0802108]
WOS研究方向Astronomy & Astrophysics ; Geology
语种英语
出版者AMER GEOPHYSICAL UNION
WOS记录号WOS:000452863600004
资助机构External Cooperation Program of Chinese Academy of Sciences ; External Cooperation Program of Chinese Academy of Sciences ; External Cooperation Program of Chinese Academy of Sciences ; External Cooperation Program of Chinese Academy of Sciences ; External Cooperation Program of Chinese Academy of Sciences ; External Cooperation Program of Chinese Academy of Sciences ; External Cooperation Program of Chinese Academy of Sciences ; External Cooperation Program of Chinese Academy of Sciences ; Special Fund for Basic Research on Scientific Instruments of the Chinese Academy of Science ; Special Fund for Basic Research on Scientific Instruments of the Chinese Academy of Science ; Special Fund for Basic Research on Scientific Instruments of the Chinese Academy of Science ; Special Fund for Basic Research on Scientific Instruments of the Chinese Academy of Science ; Special Fund for Basic Research on Scientific Instruments of the Chinese Academy of Science ; Special Fund for Basic Research on Scientific Instruments of the Chinese Academy of Science ; Special Fund for Basic Research on Scientific Instruments of the Chinese Academy of Science ; Special Fund for Basic Research on Scientific Instruments of the Chinese Academy of Science ; National Key Technology Research and Development Program of the Ministry of Science and Technology of China ; National Key Technology Research and Development Program of the Ministry of Science and Technology of China ; National Key Technology Research and Development Program of the Ministry of Science and Technology of China ; National Key Technology Research and Development Program of the Ministry of Science and Technology of China ; National Key Technology Research and Development Program of the Ministry of Science and Technology of China ; National Key Technology Research and Development Program of the Ministry of Science and Technology of China ; National Key Technology Research and Development Program of the Ministry of Science and Technology of China ; National Key Technology Research and Development Program of the Ministry of Science and Technology of China ; Science and Technology Program of Anhui Province ; Science and Technology Program of Anhui Province ; Science and Technology Program of Anhui Province ; Science and Technology Program of Anhui Province ; Science and Technology Program of Anhui Province ; Science and Technology Program of Anhui Province ; Science and Technology Program of Anhui Province ; Science and Technology Program of Anhui Province ; External Cooperation Program of Chinese Academy of Sciences ; External Cooperation Program of Chinese Academy of Sciences ; External Cooperation Program of Chinese Academy of Sciences ; External Cooperation Program of Chinese Academy of Sciences ; External Cooperation Program of Chinese Academy of Sciences ; External Cooperation Program of Chinese Academy of Sciences ; External Cooperation Program of Chinese Academy of Sciences ; External Cooperation Program of Chinese Academy of Sciences ; Special Fund for Basic Research on Scientific Instruments of the Chinese Academy of Science ; Special Fund for Basic Research on Scientific Instruments of the Chinese Academy of Science ; Special Fund for Basic Research on Scientific Instruments of the Chinese Academy of Science ; Special Fund for Basic Research on Scientific Instruments of the Chinese Academy of Science ; Special Fund for Basic Research on Scientific Instruments of the Chinese Academy of Science ; Special Fund for Basic Research on Scientific Instruments of the Chinese Academy of Science ; Special Fund for Basic Research on Scientific Instruments of the Chinese Academy of Science ; Special Fund for Basic Research on Scientific Instruments of the Chinese Academy of Science ; National Key Technology Research and Development Program of the Ministry of Science and Technology of China ; National Key Technology Research and Development Program of the Ministry of Science and Technology of China ; National Key Technology Research and Development Program of the Ministry of Science and Technology of China ; National Key Technology Research and Development Program of the Ministry of Science and Technology of China ; National Key Technology Research and Development Program of the Ministry of Science and Technology of China ; National Key Technology Research and Development Program of the Ministry of Science and Technology of China ; National Key Technology Research and Development Program of the Ministry of Science and Technology of China ; National Key Technology Research and Development Program of the Ministry of Science and Technology of China ; Science and Technology Program of Anhui Province ; Science and Technology Program of Anhui Province ; Science and Technology Program of Anhui Province ; Science and Technology Program of Anhui Province ; Science and Technology Program of Anhui Province ; Science and Technology Program of Anhui Province ; Science and Technology Program of Anhui Province ; Science and Technology Program of Anhui Province
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/40692]  
专题合肥物质科学研究院_中科院安徽光学精密机械研究所
通讯作者Zhang, Zhirong; Dong, Fengzhong
作者单位1.Yunlin Univ Sci & Technol, Grad Sch Engn Sci & Technol, Touliu, Yunlin, Taiwan
2.Univ Sci & Technol China, Sch Environm Sci & Optoelect Technol, Hefei, Anhui, Peoples R China
3.Chinese Acad Sci, Anhui Inst Opt & Fine Mech, Key Lab Environm Opt & Technol, Hefei, Anhui, Peoples R China
4.Chinese Acad Sci, Anhui Inst Opt & Fine Mech, Anhui Prov Key Lab Photon Devices & Mat, Hefei, Anhui, Peoples R China
推荐引用方式
GB/T 7714		 Zhang, Zhirong,Sun, Pengshuai,Li, Zhe,et al. Novel Coalbed Methane (CBM) Origin Analysis and Source Apportionment Method Based on Carbon Isotope Ratio Using Infrared Dual-Wavelength Laser Absorption Spectroscopy[J]. EARTH AND SPACE SCIENCE,2018,5(11):721-735.
APA Zhang, Zhirong.,Sun, Pengshuai.,Li, Zhe.,Xia, Hua.,Cui, Xiaojuan.,...&Dong, Fengzhong.(2018).Novel Coalbed Methane (CBM) Origin Analysis and Source Apportionment Method Based on Carbon Isotope Ratio Using Infrared Dual-Wavelength Laser Absorption Spectroscopy.EARTH AND SPACE SCIENCE,5(11),721-735.
MLA Zhang, Zhirong,et al."Novel Coalbed Methane (CBM) Origin Analysis and Source Apportionment Method Based on Carbon Isotope Ratio Using Infrared Dual-Wavelength Laser Absorption Spectroscopy".EARTH AND SPACE SCIENCE 5.11(2018):721-735.

入库方式： OAI收割

来源：合肥物质科学研究院

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