中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Molecular Dynamics of Hexamethylbenzene at Low Temperatures: Evidence of Unconventional Magnetism Based on Rotational Motion of Protons

文献类型:期刊论文

作者Yen, Fei1,2; Zhao, Zhenzheng4; Hu, Sixia3; Chen, Lang2
刊名ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
出版日期2017-10-23
卷号56期号:44页码:13675-13678
关键词antiferromagnetism low-temperature physics phase transitions proton tunneling strongly correlated systems
ISSN号1433-7851
DOI10.1002/anie.201707024
英文摘要

The types of magnetism known to date are all mainly based on contributions from electron motion. We show how rotational motion of protons (H+) within the methyl groups in hexamethylbenzene (C-6(CH3)(6)) also contribute significantly to the magnetic susceptibility. Starting from below 118 K, as the rotational motion of the methyl groups set in, an associated magnetic moment positive in nature due to charge of the protons renders the susceptibility to become anomalously dependent on temperature. Starting from 20 K, the susceptibility diverges with decreasing temperature indicative of spin-spin interactions between methyl groups aligned in a previously unclassified type of anti-ferromagnetic configuration. Complementary dielectric constant measurements also show the existence of magneto-dielectric coupling. Our findings allow for the study of strongly correlated systems that are based on a species that possesses much slower dynamics.

WOS关键词METHYL-GROUPS ; PHASE-DIAGRAMS ; HEAT-CAPACITY ; RESONANCE ; ICE ; CRYSTALLINE ; RING ; H2O
资助项目NSFC (National Natural Science Foundation of China)[11374307] ; NSFC (National Natural Science Foundation of China)[11250110050] ; NSFC (National Natural Science Foundation of China)[11474146] ; NSFC (National Natural Science Foundation of China)[11504161] ; NSFC (National Natural Science Foundation of China)[11650110430] ; NSFC (National Natural Science Foundation of China)[U1532142] ; Hong Kong, Macao and Taiwan Science and Technology Cooperation Program of China[2015DFH10200] ; Science and Technology Research Items of Shenzhen[JCYJ20140417105742706] ; Science and Technology Research Items of Shenzhen[KQCX2014052215132294] ; Science and Technology Research Items of Shenzhen[JCYJ20160530185705301] ; Science and Technology Research Items of Shenzhen[JCYJ20170412153325679] ; Nanshan Key Laboratory Support program
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000413314800021
出版者WILEY-V C H VERLAG GMBH
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/36169]  
专题合肥物质科学研究院_中科院固体物理研究所
通讯作者Yen, Fei; Chen, Lang
作者单位1.Chinese Acad Sci, Hefei Inst Phys Sci, Inst Solid State Phys, Hefei 230031, Anhui, Peoples R China
2.Southern Univ Sci & Technol, Dept Phys, 1088 Xueyuan Blvd, Shenzhen 518055, Guangdong, Peoples R China
3.Southern Univ Sci & Technol, Mat Characterizat & Preparat Ctr, 1088 Xueyuan Blvd, Shenzhen 518055, Guangdong, Peoples R China
4.Harbin Inst Technol, Dept Phys, 92 West Da Zhi St, Harbin 150001, Heilongjiang, Peoples R China
推荐引用方式
GB/T 7714
Yen, Fei,Zhao, Zhenzheng,Hu, Sixia,et al. Molecular Dynamics of Hexamethylbenzene at Low Temperatures: Evidence of Unconventional Magnetism Based on Rotational Motion of Protons[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(44):13675-13678.
APA Yen, Fei,Zhao, Zhenzheng,Hu, Sixia,&Chen, Lang.(2017).Molecular Dynamics of Hexamethylbenzene at Low Temperatures: Evidence of Unconventional Magnetism Based on Rotational Motion of Protons.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(44),13675-13678.
MLA Yen, Fei,et al."Molecular Dynamics of Hexamethylbenzene at Low Temperatures: Evidence of Unconventional Magnetism Based on Rotational Motion of Protons".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.44(2017):13675-13678.

入库方式: OAI收割

来源:合肥物质科学研究院

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