Molecular Dynamics of Hexamethylbenzene at Low Temperatures: Evidence of Unconventional Magnetism Based on Rotational Motion of Protons
文献类型:期刊论文
作者 | Yen, Fei1,2; Zhao, Zhenzheng4; Hu, Sixia3; Chen, Lang2 |
刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
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出版日期 | 2017-10-23 |
卷号 | 56期号:44页码:13675-13678 |
关键词 | antiferromagnetism low-temperature physics phase transitions proton tunneling strongly correlated systems |
ISSN号 | 1433-7851 |
DOI | 10.1002/anie.201707024 |
英文摘要 | The types of magnetism known to date are all mainly based on contributions from electron motion. We show how rotational motion of protons (H+) within the methyl groups in hexamethylbenzene (C-6(CH3)(6)) also contribute significantly to the magnetic susceptibility. Starting from below 118 K, as the rotational motion of the methyl groups set in, an associated magnetic moment positive in nature due to charge of the protons renders the susceptibility to become anomalously dependent on temperature. Starting from 20 K, the susceptibility diverges with decreasing temperature indicative of spin-spin interactions between methyl groups aligned in a previously unclassified type of anti-ferromagnetic configuration. Complementary dielectric constant measurements also show the existence of magneto-dielectric coupling. Our findings allow for the study of strongly correlated systems that are based on a species that possesses much slower dynamics. |
WOS关键词 | METHYL-GROUPS ; PHASE-DIAGRAMS ; HEAT-CAPACITY ; RESONANCE ; ICE ; CRYSTALLINE ; RING ; H2O |
资助项目 | NSFC (National Natural Science Foundation of China)[11374307] ; NSFC (National Natural Science Foundation of China)[11250110050] ; NSFC (National Natural Science Foundation of China)[11474146] ; NSFC (National Natural Science Foundation of China)[11504161] ; NSFC (National Natural Science Foundation of China)[11650110430] ; NSFC (National Natural Science Foundation of China)[U1532142] ; Hong Kong, Macao and Taiwan Science and Technology Cooperation Program of China[2015DFH10200] ; Science and Technology Research Items of Shenzhen[JCYJ20140417105742706] ; Science and Technology Research Items of Shenzhen[KQCX2014052215132294] ; Science and Technology Research Items of Shenzhen[JCYJ20160530185705301] ; Science and Technology Research Items of Shenzhen[JCYJ20170412153325679] ; Nanshan Key Laboratory Support program |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000413314800021 |
出版者 | WILEY-V C H VERLAG GMBH |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/36169] ![]() |
专题 | 合肥物质科学研究院_中科院固体物理研究所 |
通讯作者 | Yen, Fei; Chen, Lang |
作者单位 | 1.Chinese Acad Sci, Hefei Inst Phys Sci, Inst Solid State Phys, Hefei 230031, Anhui, Peoples R China 2.Southern Univ Sci & Technol, Dept Phys, 1088 Xueyuan Blvd, Shenzhen 518055, Guangdong, Peoples R China 3.Southern Univ Sci & Technol, Mat Characterizat & Preparat Ctr, 1088 Xueyuan Blvd, Shenzhen 518055, Guangdong, Peoples R China 4.Harbin Inst Technol, Dept Phys, 92 West Da Zhi St, Harbin 150001, Heilongjiang, Peoples R China |
推荐引用方式 GB/T 7714 | Yen, Fei,Zhao, Zhenzheng,Hu, Sixia,et al. Molecular Dynamics of Hexamethylbenzene at Low Temperatures: Evidence of Unconventional Magnetism Based on Rotational Motion of Protons[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(44):13675-13678. |
APA | Yen, Fei,Zhao, Zhenzheng,Hu, Sixia,&Chen, Lang.(2017).Molecular Dynamics of Hexamethylbenzene at Low Temperatures: Evidence of Unconventional Magnetism Based on Rotational Motion of Protons.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(44),13675-13678. |
MLA | Yen, Fei,et al."Molecular Dynamics of Hexamethylbenzene at Low Temperatures: Evidence of Unconventional Magnetism Based on Rotational Motion of Protons".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.44(2017):13675-13678. |
入库方式: OAI收割
来源:合肥物质科学研究院
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