Facile Preparation of Amorphous Fe-Co-Ni Hydroxide Arrays: A Highly Efficient Integrated Electrode for Water Oxidation
文献类型:期刊论文
作者 | Liu, Qilong1,4; Zhang, Hang1,4; Xu, Jie1,4; Wei, Lingzhi2; Liu, Qiangchun1,4; Kong, Xiangkai1,3,4 |
刊名 | INORGANIC CHEMISTRY |
出版日期 | 2018-12-17 |
卷号 | 57期号:24页码:15610-15617 |
ISSN号 | 0020-1669 |
DOI | 10.1021/acs.inorgchem.8b03063 |
通讯作者 | Liu, Qiangchun(qchliu@chnu.edu.cn) ; Kong, Xiangkai(kxk@chnu.edu.cn) |
英文摘要 | Facile and fast synthesis of functional materials with high catalytic activity is highly demanded to meet the industrial production and applications such as electrolysis. In this study, Ni foam is employed as the current collector and Ni source, which is dipped into the mixture of Fe and Co metal ions solution at room temperature for several minutes, to in situ grow Fe-Co-Ni hydroxide arrays and construct the three-dimensional integrated electrode. This short-time preparation at room temperature is beneficial to avoid the rapid growth of the generated primary nanocrystallites and cause intimate interactions between Fe, Co, and Ni atoms. The obtained self supported and vertically aligned Fe-Co-Ni hydroxides present an amorphous phase, which exhibit high activity with low overpotentials of 212 mV at 10 mA cm(-2) and 319 mV at 100 mA cm(-2), associated with a small Tafel slope of 52 mV dec(-1) toward the oxygen evolution reaction. |
WOS关键词 | OXYGEN-EVOLUTION ELECTROCATALYSTS ; HYDROGEN EVOLUTION ; NANOSHEET ARRAY ; NANOWIRE ARRAY ; CARBON PAPER ; REDUCTION ; CATALYSTS ; CATHODE ; FILM |
资助项目 | National Natural Science Foundation of China[51602116] ; Natural Science Foundation of Anhui Province[1708085QB40] ; China Postdoctoral Science Foundation[2016M600492] |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000453938700061 |
资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Natural Science Foundation of Anhui Province ; Natural Science Foundation of Anhui Province ; Natural Science Foundation of Anhui Province ; Natural Science Foundation of Anhui Province ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Natural Science Foundation of Anhui Province ; Natural Science Foundation of Anhui Province ; Natural Science Foundation of Anhui Province ; Natural Science Foundation of Anhui Province ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/40683] |
专题 | 合肥物质科学研究院_中科院强磁场科学中心 |
通讯作者 | Liu, Qiangchun; Kong, Xiangkai |
作者单位 | 1.Huaibei Normal Univ, Collaborat Innovat Ctr Adv Funct Composites, Huaibei 235000, Anhui, Peoples R China 2.Anhui Univ, Ctr Modern Expt & Technol, Hefei 230601, Anhui, Peoples R China 3.Chinese Acad Sci, High Field Magnet Lab, Hefei 230031, Anhui, Peoples R China 4.Huaibei Normal Univ, Sch Phys & Elect Informat, Huaibei 235000, Anhui, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Qilong,Zhang, Hang,Xu, Jie,et al. Facile Preparation of Amorphous Fe-Co-Ni Hydroxide Arrays: A Highly Efficient Integrated Electrode for Water Oxidation[J]. INORGANIC CHEMISTRY,2018,57(24):15610-15617. |
APA | Liu, Qilong,Zhang, Hang,Xu, Jie,Wei, Lingzhi,Liu, Qiangchun,&Kong, Xiangkai.(2018).Facile Preparation of Amorphous Fe-Co-Ni Hydroxide Arrays: A Highly Efficient Integrated Electrode for Water Oxidation.INORGANIC CHEMISTRY,57(24),15610-15617. |
MLA | Liu, Qilong,et al."Facile Preparation of Amorphous Fe-Co-Ni Hydroxide Arrays: A Highly Efficient Integrated Electrode for Water Oxidation".INORGANIC CHEMISTRY 57.24(2018):15610-15617. |
入库方式: OAI收割
来源:合肥物质科学研究院
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