Catalytic conversion of carbohydrates into 5-hydroxymethyl furfural over sulfonated hyper-cross-linked polymer in DMSO
文献类型：期刊论文
| 作者 | Dong, Kaijun1,2,3 ; Zhang, Jun1,2,3; Luo, Weimin1,2,3; Su, Lin1,2,3; Huang, Zhilin1,2,3,4
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| 刊名 | CHEMICAL ENGINEERING JOURNAL
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| 出版日期 | 2018-02-15 |
| 卷号 | 334页码:1055-1064 |
| 关键词 | Hyper-cross-linked polymer Carbohydrates Dehydration 5-Hydroxymethyl furfural |
| ISSN号 | 1385-8947 |
| DOI | 10.1016/j.cej.2017.10.092 |
| 通讯作者 | Zhang, Jun(zhangjun@ms.giec.ac.cn) |
| 英文摘要 | An acid functionalized porous organic hyper-cross-linked polymer (HCP) derived from benzene monomer was prepared for catalytic dehydration of carbohydrates into 5-hydroxymethyl furfural (HMF) in a DMSO solvent. Systematic characterizations of the HCP catalysts including essential structural properties, sulfur content and acid amount, were identified by XRD, XPS, FESEM, Raman, NH3-TPD, TGA, nitrogen physisorption and elemental analysis. Optimization of reaction parameters such as acid amount, solvent, substrate type, temperature and catalyst dosage, and comparison with reported solid acids were systematically investigated. The results showed that sulfonated HCP materials were highly active in fructose dehydration, which could afford a highest HMF yield of 96.7% at almost 100% fructose conversion in 30 min. Furthermore, the catalyst presented satisfied performance and stability during recycling tests. More importantly, the sulfonated HCP catalysts also exhibited promising activity in hydrolytic reaction, esterification and transesterification for platform chemicals production in biomass transformation. |
| WOS关键词 | SOLID ACID CATALYSTS ; ION-EXCHANGE-RESIN ; D-FRUCTOSE ; SELECTIVE CONVERSION ; BIODIESEL PRODUCTION ; MESOPOROUS SILICA ; LEVULINIC ACID ; DEHYDRATION ; GLUCOSE ; WATER |
| 资助项目 | Natural Science Foundation of Guangdong Province, China[2014A030310386] ; Natural Science Foundation of Guangdong Province, China[2016A030313173] ; Science and Technology Planning Project of Guangdong Province, China[2015A040404039] ; Science and Technology Planning Project of Guangdong Province, China[2015B090901012] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000418533400104 |
| 出版者 | ELSEVIER SCIENCE SA |
| 资助机构 | Natural Science Foundation of Guangdong Province, China ; Science and Technology Planning Project of Guangdong Province, China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/22754]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Zhang, Jun |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dong, Kaijun,Zhang, Jun,Luo, Weimin,et al. Catalytic conversion of carbohydrates into 5-hydroxymethyl furfural over sulfonated hyper-cross-linked polymer in DMSO[J]. CHEMICAL ENGINEERING JOURNAL,2018,334:1055-1064. |
| APA | Dong, Kaijun,Zhang, Jun,Luo, Weimin,Su, Lin,&Huang, Zhilin.(2018).Catalytic conversion of carbohydrates into 5-hydroxymethyl furfural over sulfonated hyper-cross-linked polymer in DMSO.CHEMICAL ENGINEERING JOURNAL,334,1055-1064. |
| MLA | Dong, Kaijun,et al."Catalytic conversion of carbohydrates into 5-hydroxymethyl furfural over sulfonated hyper-cross-linked polymer in DMSO".CHEMICAL ENGINEERING JOURNAL 334(2018):1055-1064. |
入库方式： OAI收割
来源：广州能源研究所
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