Lignin-first depolymerization of native corn stover with an unsupported MoS2 catalyst
文献类型：期刊论文
| 作者 | Li, Song1,2,3,4; Li, Wenzhi5; Zhang, Qi2,3,4 ; Shu, Riyang2,3,4; Wang, Huizhen5; Xin, Haosheng5; Ma, Longlong2,3,4
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| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2018 |
| 卷号 | 8期号:3页码:1361-1370 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c7ra11947j |
| 通讯作者 | Li, Wenzhi(liwenzhi@ustc.edu.cn) ; Zhang, Qi(zhangqi@ms.giec.ac.cn) |
| 英文摘要 | The lignin-first biorefinery method appears to be an attractive approach to produce phenolic chemicals. Herein, corn stover was employed for the production of phenolic monomers using an unsupported non-noble MoS2 catalyst. The yield of phenolic monomers was enhanced from 6.65% to 18.47% with MoS2 at 250 degrees C and about 75% lignin was degraded with more than 90% glucan reserved in the solid residues. The Fourier-Transform Infrared (FT-IR) and heteronuclear single quantum coherence-nuclear magnetic resonance (H-1-C-13 HSQC-NMR) characterization suggested that the cleavage of the beta-O-4, gamma-ester and benzyl ether linkages were enhanced, promoting the delignification and the depolymerization of lignin. The catalyst performance was relatively effective with 14.30% phenolic monomer yield after the fifth run. The effects of the reaction temperature, the initial hydrogen pressure, the dosage of catalyst, and the reaction time were investigated. The model reactions were also proposed for the potential mechanism study. This work provides some basic information for the improvement of the graminaceous plant lignin-first process with a non-noble metal catalyst. |
| WOS关键词 | NOBLE-METAL CATALYSTS ; KRAFT LIGNIN ; REDUCTIVE FRACTIONATION ; HYDROGENOLYSIS PROCESS ; HYDROTHERMAL SYNTHESIS ; PD/C CATALYST ; WOODY BIOMASS ; BIO-OIL ; VALORIZATION ; ACID |
| 资助项目 | Program of National Natural Science Foundation of China[51476178] ; Program of National Natural Science Foundation of China[51536009] ; National Key Technology R&D Program of China[2015BAD15B06] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000419371200025 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | Program of National Natural Science Foundation of China ; National Key Technology R&D Program of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/22828]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Li, Wenzhi; Zhang, Qi |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 3.CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 4.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China 5.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Lab Basic Res Biomass Convers & Utilizat, Hefei 230026, Anhui, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Song,Li, Wenzhi,Zhang, Qi,et al. Lignin-first depolymerization of native corn stover with an unsupported MoS2 catalyst[J]. RSC ADVANCES,2018,8(3):1361-1370. |
| APA | Li, Song.,Li, Wenzhi.,Zhang, Qi.,Shu, Riyang.,Wang, Huizhen.,...&Ma, Longlong.(2018).Lignin-first depolymerization of native corn stover with an unsupported MoS2 catalyst.RSC ADVANCES,8(3),1361-1370. |
| MLA | Li, Song,et al."Lignin-first depolymerization of native corn stover with an unsupported MoS2 catalyst".RSC ADVANCES 8.3(2018):1361-1370. |
入库方式： OAI收割
来源：广州能源研究所
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