N-cyanoethyl polyethylenimine as a water-soluble binder for LiFePO4 cathode in lithium-ion batteries
文献类型：期刊论文
| 作者 | Huang, Jinxin1,2; Wang, Jinglun2 ; Zhong, Haoxiang2; Zhang, Lingzhi2
|
| 刊名 | JOURNAL OF MATERIALS SCIENCE
 |
| 出版日期 | 2018-07-01 |
| 卷号 | 53期号:13页码:9690-9700 |
| ISSN号 | 0022-2461 |
| DOI | 10.1007/s10853-018-2247-y |
| 通讯作者 | Zhang, Lingzhi(lzzhang@ms.giec.ac.cn) |
| 英文摘要 | N-cyanoethyl polyethylenimine (CN-PEI) is synthesized by modifying polyethylenimine (PEI) with acrylonitrile through a Michael addition reaction. Depending on cyanoethylation level, CN-PEI can be obtained as a form of solution, micro-emulsion or emulsion in water. CN-PEI micro-emulsion is investigated as water-soluble binder for the application of lithium iron phosphate (LFP) cathode in lithium-ion batteries. CN-PEI binder not only maintains the outstanding dispersion capability of PEI but also exhibits an excellent adhesion strength and higher ionic conductivity because of the introduction of polar cyano groups. As a result, CN-PEI binder can effectively maintain the mechanical integrity and decrease the polarization of LFP electrode during the operation of the battery. LFP electrode with CN-PEI binder exhibits good cycle stability and enhanced rate performance delivering a capacity of 99.6% at a rate of 0.5 C after 100 cycles and a high discharge capacity of 102.4 mAh g(-1) at 5 C. |
| WOS关键词 | HIGH POLAR POLYACRYLONITRILE ; CARBOXYMETHYL CHITOSAN ; NEGATIVE ELECTRODES ; POLYMER ; ELECTROLYTES ; ANODES ; RAMAN |
| 资助项目 | K.C. Wong Education Foundation ; National Natural Science Foundation of China[21573239] ; Science & Technology project of Guangdong Province[2014TX01N014/2015B010135008] ; Guangzhou Municipal Project for Science Technology[201509010018] |
| WOS研究方向 | Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000430171400026 |
| 出版者 | SPRINGER |
| 资助机构 | K.C. Wong Education Foundation ; National Natural Science Foundation of China ; Science & Technology project of Guangdong Province ; Guangzhou Municipal Project for Science Technology |
| 源URL | [http://ir.giec.ac.cn/handle/344007/23029]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Zhang, Lingzhi |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Jinxin,Wang, Jinglun,Zhong, Haoxiang,et al. N-cyanoethyl polyethylenimine as a water-soluble binder for LiFePO4 cathode in lithium-ion batteries[J]. JOURNAL OF MATERIALS SCIENCE,2018,53(13):9690-9700. |
| APA | Huang, Jinxin,Wang, Jinglun,Zhong, Haoxiang,&Zhang, Lingzhi.(2018).N-cyanoethyl polyethylenimine as a water-soluble binder for LiFePO4 cathode in lithium-ion batteries.JOURNAL OF MATERIALS SCIENCE,53(13),9690-9700. |
| MLA | Huang, Jinxin,et al."N-cyanoethyl polyethylenimine as a water-soluble binder for LiFePO4 cathode in lithium-ion batteries".JOURNAL OF MATERIALS SCIENCE 53.13(2018):9690-9700. |
入库方式： OAI收割
来源：广州能源研究所
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