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Catalytic Transfer Hydrogenation of Ethyl Levulinate into gamma-Valerolactone Over Zirconium Oxide Derived from Zirconyl Nitrate

文献类型：期刊论文

作者Dong, Kaijun1,3,4; Zhang, Jun1,3,4; Luo, Weimin1,3,4; Su, Lin1,3,4; Huang, Zhilin1,2,3,4
刊名JOURNAL OF BIOBASED MATERIALS AND BIOENERGY
出版日期2017-12-01
卷号11期号:6页码:543-552
关键词gamma-Valerolactone Hydrogen Donors Zirconium Oxide Zirconyl Nitrate
ISSN号1556-6560
DOI10.1166/jbmb.2017.1717
通讯作者Zhang, Jun(zhangjun@ms.giec.ac.cn)
英文摘要A series of zirconium based catalysts were synthesized to study the transfer hydrogenation of biomass derived ethyl levulinate into gamma-valerolactone (GVL) using lower alcohols as hydrogen donors. The essential textural and chemical characteristics of prepared samples were identified by various techniques including SEM, XRD, NH3-TPD, TGA, CO2-TPD and nitrogen physisorption. Parameters such as hydrogen donor, catalyst type, temperature, stirring rate, and catalyst dosage were found to play a critical role in GVL production. A promising GVL yield of 98.3 mol% with a highest GVL formation rate at 5239.4 mu mol g(cat)(-1) h(-1) was obtained in isopropanol at 433 K over zirconium oxide derived from zirconyl nitrate. The recycling experiments revealed that the zirconium oxide catalyst derived from zirconyl nitrate presented relatively satisfied performance and stability.
WOS关键词MEERWEIN-PONNDORF-VERLEY ; BIOMASS ; CONVERSION ; ACID ; EFFICIENT ; ESTERS ; REDUCTIONS
资助项目Natural Science Foundation of Guangdong Province, China[2014A030310386] ; Natural Science Foundation of Guangdong Province, China[2016A030313173] ; Natural Science Foundation of Guangdong Province, China[2015A030310408] ; Science and Technology Planning Project of Guangdong Province, China[2015A040404039] ; Science and Technology Planning Project of Guangdong Province, China[2015B 090901012]
WOS研究方向Chemistry ; Energy & Fuels ; Materials Science
语种英语
WOS记录号WOS:000430408000002
出版者AMER SCIENTIFIC PUBLISHERS
资助机构Natural Science Foundation of Guangdong Province, China ; Science and Technology Planning Project of Guangdong Province, China
源URL[http://ir.giec.ac.cn/handle/344007/23180]  
专题中国科学院广州能源研究所
通讯作者Zhang, Jun
作者单位1.CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
4.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式
GB/T 7714		 Dong, Kaijun,Zhang, Jun,Luo, Weimin,et al. Catalytic Transfer Hydrogenation of Ethyl Levulinate into gamma-Valerolactone Over Zirconium Oxide Derived from Zirconyl Nitrate[J]. JOURNAL OF BIOBASED MATERIALS AND BIOENERGY,2017,11(6):543-552.
APA Dong, Kaijun,Zhang, Jun,Luo, Weimin,Su, Lin,&Huang, Zhilin.(2017).Catalytic Transfer Hydrogenation of Ethyl Levulinate into gamma-Valerolactone Over Zirconium Oxide Derived from Zirconyl Nitrate.JOURNAL OF BIOBASED MATERIALS AND BIOENERGY,11(6),543-552.
MLA Dong, Kaijun,et al."Catalytic Transfer Hydrogenation of Ethyl Levulinate into gamma-Valerolactone Over Zirconium Oxide Derived from Zirconyl Nitrate".JOURNAL OF BIOBASED MATERIALS AND BIOENERGY 11.6(2017):543-552.

入库方式： OAI收割

来源：广州能源研究所

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