Crystal morphology-based kinetic study of carbon dioxide-hydrogen-tetra-n-butyl ammonium bromide hydrates formation in a static system
文献类型：期刊论文
| 作者 | Yu, Yi-Song1,2,3; Xu, Chun-Gang2,3; Li, Xiao-Sen2,3
|
| 刊名 | ENERGY
 |
| 出版日期 | 2018-01-15 |
| 卷号 | 143页码:546-553 |
| 关键词 | TBAB Morphology Induction time Split fraction CO2 separation IGCC syngas |
| ISSN号 | 0360-5442 |
| DOI | 10.1016/j.energy.2017.10.117 |
| 通讯作者 | Li, Xiao-Sen(lixs@ms.giec.ac.cn) |
| 英文摘要 | Hydrate based CO2 separation process is affected by many factors which mainly includes additive concentration, gas-liquid volume ratio and operating conditions. The most of the investigations on the CO2 hydrate-based separation in the previous work were carried out around the kinetics and thermodynamics of the hydrate formation along with the CO2 separation efficiency. However, few studies focus on the morphology of hydrate though the difference of the morphologies directly leads to the difference of the CO2 separation efficiency. In this work, the morphology along with the kinetics of the hydrate-based CO2 separation from CO2/H-2 (40%/60%) is carried out in the presence of tetra-n-butyl ammonium bromide (TBAB) of 0.29 mol%. The results indicate, firstly, TBAB hydrate formation and TBAB/gas mixture hydrate formation were two independent processes. Secondly, the different operating conditions resulted in different hydrate morphologies. Thirdly, the consumption of CO2 in low pressure (<2.5 MPa) was controlled by the driving force, while that was controlled by the formed hydrate layer in the gas liquid interface in the relatively high pressure especially for the initial pressure >= 4.5 MPa. (C) 2017 Elsevier Ltd. All rights reserved. |
| WOS关键词 | PRE-COMBUSTION CAPTURE ; NATURAL-GAS HYDRATE ; CO2 CAPTURE ; FLUE-GAS ; SEPARATION ; MIXTURE ; CYCLOPENTANE ; RECOVERY ; SYNGAS ; ENERGY |
| 资助项目 | National Natural Science Foundation of China[51736009] ; International S&T Cooperation Program of China[2015DFA61790] ; Chinese Academy of Sciences[YZ201619] ; Chinese Academy of Sciences[QYZDJ-SSW-JSC033] |
| WOS研究方向 | Thermodynamics ; Energy & Fuels |
| 语种 | 英语 |
| WOS记录号 | WOS:000425565700044 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 资助机构 | National Natural Science Foundation of China ; International S&T Cooperation Program of China ; Chinese Academy of Sciences |
| 源URL | [http://ir.giec.ac.cn/handle/344007/23268]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Li, Xiao-Sen |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci Guangzhou, Guangzhou Inst Energy Convers, Key Lab Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, Yi-Song,Xu, Chun-Gang,Li, Xiao-Sen. Crystal morphology-based kinetic study of carbon dioxide-hydrogen-tetra-n-butyl ammonium bromide hydrates formation in a static system[J]. ENERGY,2018,143:546-553. |
| APA | Yu, Yi-Song,Xu, Chun-Gang,&Li, Xiao-Sen.(2018).Crystal morphology-based kinetic study of carbon dioxide-hydrogen-tetra-n-butyl ammonium bromide hydrates formation in a static system.ENERGY,143,546-553. |
| MLA | Yu, Yi-Song,et al."Crystal morphology-based kinetic study of carbon dioxide-hydrogen-tetra-n-butyl ammonium bromide hydrates formation in a static system".ENERGY 143(2018):546-553. |
入库方式： OAI收割
来源：广州能源研究所
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