Controllable production of guaiacols and phenols from lignin depolymerization using Pd/C catalyst cooperated with metal chloride
文献类型：期刊论文
| 作者 | Shu, Riyang1,2; Xu, Ying1 ; Ma, Longlong1; Zhang, Qi1; Wang, Chao2; Chen, Ying2
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| 刊名 | CHEMICAL ENGINEERING JOURNAL
 |
| 出版日期 | 2018-04-15 |
| 卷号 | 338页码:457-464 |
| 关键词 | Lignin Hydrogenolysis Controllable product distribution beta-O-4 Synergetic catalysis Lewis acid |
| ISSN号 | 1385-8947 |
| DOI | 10.1016/j.cej.2018.01.002 |
| 通讯作者 | Zhang, Qi(zhangqi@ms.giec.ac.cn) ; Chen, Ying(chenying@gdut.edu.cn) |
| 英文摘要 | Many effective methods have been proposed to achieve lignin depolymerization, while controllable product distribution is still hard to realize. Herein, an efficient lignin hydrogenolysis process with controllable product distribution was put forward using Pd/C catalyst cooperated with metal chloride. Results showed that lignin produced a high amount of guaiacols in the presence of ZnCl2, while a high amount of phenols in the presence of CrCl3. Guaiacylglycerol-beta-guaiacyl ether was used as the model compound to carry out the mechanistic investigation. A synergetic catalysis effect between Pd/C and metal chloride was exhibited in this process. And the Lewis acidity was an important factor to determine the product distribution. With the synergetic catalysis of Pd/C and metal chloride, the dissociation energy of beta-O-4 bond was reduced significantly, which made the cleavage easier to realize. The phenolic monomer product of guaiacols was produced in the initial stage. Then CrCl3 catalyst with strong Lewis acidity could further promote the occurrence of demethoxylation and alkylation, converting the guaiacols into phenols. This work figures out the mechanism of product control in the hydrogenolysis process and displays a clear potential for the controllable valorization of lignin. |
| WOS关键词 | AQUEOUS-PHASE HYDRODEOXYGENATION ; HYDROGENOLYSIS PROCESS ; MODEL COMPOUNDS ; HYDROLYZED LIGNIN ; AROMATIC MONOMERS ; IONIC LIQUIDS ; FORMIC-ACID ; WOOD LIGNIN ; NOBLE-METAL ; DEGRADATION |
| 资助项目 | Natural Science Foundation of China[51476178] ; Natural Science Foundation of China[51676191] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000427618400047 |
| 出版者 | ELSEVIER SCIENCE SA |
| 资助机构 | Natural Science Foundation of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/23272]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Zhang, Qi; Chen, Ying |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Guangdong Univ Technol, Sch Mat & Energy, Guangdong Prov Key Lab Funct Soft Condensed Matte, Guangzhou 510006, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shu, Riyang,Xu, Ying,Ma, Longlong,et al. Controllable production of guaiacols and phenols from lignin depolymerization using Pd/C catalyst cooperated with metal chloride[J]. CHEMICAL ENGINEERING JOURNAL,2018,338:457-464. |
| APA | Shu, Riyang,Xu, Ying,Ma, Longlong,Zhang, Qi,Wang, Chao,&Chen, Ying.(2018).Controllable production of guaiacols and phenols from lignin depolymerization using Pd/C catalyst cooperated with metal chloride.CHEMICAL ENGINEERING JOURNAL,338,457-464. |
| MLA | Shu, Riyang,et al."Controllable production of guaiacols and phenols from lignin depolymerization using Pd/C catalyst cooperated with metal chloride".CHEMICAL ENGINEERING JOURNAL 338(2018):457-464. |
入库方式： OAI收割
来源：广州能源研究所
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