Selective yields of furfural and hydroxymethylfurfural from glucose in tetrahydrofuran over H beta zeolite
文献类型：期刊论文
| 作者 | Tan, Jin1,2,3; Wang, Haiyong1,2,3; Ma, Longlong1,2,3 ; Wang, Chenguang1,2,3; Liu, Qiying1,2,3; Zhang, Qi1,2,3; He, Minghong1,2,3
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| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2018 |
| 卷号 | 8期号:43页码:24534-24540 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c8ra04060e |
| 通讯作者 | Ma, Longlong(mall@ms.giec.ac.cn) |
| 英文摘要 | Several simple and effective solvents combined with H beta zeolite were tested to selectively convert glucose into furfural and hydroxymethylfurfural in this work. The physicochemical properties of typically different polar aprotic solvents were compared. Tetrahydrofuran was found to be a suitable solvent in the selective conversion of glucose. The effect of reaction parameters, such as temperature, reaction time, water content, glucose dosage and protonic acid addition, on the product distribution were investigated in detail. Furfural and hydroxymethylfurfural could be selectively produced in this system, and the highest yields of furfural and hydroxymethylfurfural were up to 35.2% and 49.7% respectively. Furfural could be stable in a tetrahydrofuran medium when adding 5 wt% water in the absence of extra protonic acid. However, furfural production was extremely suppressed after addition of an acidic inorganic salt, which increased the yield of hydroxymethylfurfural. This investigation indicates a simple and feasible method to selectively produce furfural and hydroxymethylfurfural from renewable cellulosic carbohydrates. |
| WOS关键词 | BIOMASS CONVERSION REACTIONS ; ACID-CATALYZED CONVERSION ; GAMMA-VALEROLACTONE ; LEVULINIC ACID ; SUPERCRITICAL WATER ; ETHYL LEVULINATE ; BIPHASIC SYSTEM ; SOLVENT ; FRUCTOSE ; DEHYDRATION |
| 资助项目 | National Natural Science Foundation of China[51536009] ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01N092] ; Natural Science Foundation of Guangdong Province[2017A030308010] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000440243600051 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | National Natural Science Foundation of China ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program ; Natural Science Foundation of Guangdong Province |
| 源URL | [http://ir.giec.ac.cn/handle/344007/23676]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Ma, Longlong |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tan, Jin,Wang, Haiyong,Ma, Longlong,et al. Selective yields of furfural and hydroxymethylfurfural from glucose in tetrahydrofuran over H beta zeolite[J]. RSC ADVANCES,2018,8(43):24534-24540. |
| APA | Tan, Jin.,Wang, Haiyong.,Ma, Longlong.,Wang, Chenguang.,Liu, Qiying.,...&He, Minghong.(2018).Selective yields of furfural and hydroxymethylfurfural from glucose in tetrahydrofuran over H beta zeolite.RSC ADVANCES,8(43),24534-24540. |
| MLA | Tan, Jin,et al."Selective yields of furfural and hydroxymethylfurfural from glucose in tetrahydrofuran over H beta zeolite".RSC ADVANCES 8.43(2018):24534-24540. |
入库方式： OAI收割
来源：广州能源研究所
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