Enhanced catalytic activity of Ni-Mo2C/La2O3-ZrO2 bifunctional catalyst for dry reforming of methane
文献类型：期刊论文
| 作者 | Tao, Qingqing1,2,3,4; Wang, Zhida2; Jayasundera, Bandara2; Guo, Changqing1,2,4 ; Gan, Yuan2; Zhang, Liang2; Lu, Zhuoxin2; Tan, Hongyi2; Yan, Changfeng1,2,4
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| 刊名 | JOURNAL OF MATERIALS SCIENCE
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| 出版日期 | 2018-10-01 |
| 卷号 | 53期号:20页码:14559-14572 |
| ISSN号 | 0022-2461 |
| DOI | 10.1007/s10853-018-2642-4 |
| 通讯作者 | Yan, Changfeng(yancf@ms.giec.ac.cn) |
| 英文摘要 | A series of Ni-modified Mo2C catalysts with La2O3-stabilized ZrO2 supports were synthesized via template method coupled with incipient wetness impregnation and temperature-programmed carbonization. The catalyst was tested in dry reforming of methane (DRM) reaction at the temperature range from 973 to 1173 K in a fixed-bed quartz reactor under atmospheric pressure. XRD, Raman, BET, H-2-TPD, SEM, EDS and TEM were conducted to characterize the phase constitution, the pore structure, the morphology and the crystal structure of the catalysts. N-Mo2C nanoparticles of similar to 3 nm diameter were obtained for these catalysts, and the La2O3-ZrO2 supports exhibited a cubic lattice structure with a sheet shape, which is believed to contain an abundant of oxygen vacancies. And the synergistic interaction between the oxygen vacancy in La-Zr-O solid solution and the Ni-Mo2C particles could decrease the apparent activation energy of CO2. Both of them are beneficial for accelerating DRM reaction. CH4 conversion of the best specimen catalyst reaches 94% at 1173 K, and the catalyst maintains its stability after 100-h reaction. The superior catalytic activity of NMLZ-7.5 is attributed to the improved BET surface area (33.2 m(2)/g), smaller crystallites, grain boundaries and oxidation-carbonization cycle of Ni-Mo2C. |
| WOS关键词 | SUPPORTED NI CATALYST ; MOLYBDENUM CARBIDE CATALYSTS ; CARBON-DIOXIDE ; HYDROGEN-PRODUCTION ; SYNTHESIS GAS ; PARTIAL OXIDATION ; SYNGAS PRODUCTION ; STABLE CATALYSTS ; REACTION PATHWAY ; ZIRCONIA |
| 资助项目 | Natural Science Foundation of Guangdong Province[2015A030312007] ; National Natural Science Foundation of China[51576201] ; Key Lab of Renewable Energy Foundation of Chinese Academy of Sciences[Y707j81001] ; Key Lab of Renewable Energy Foundation of Chinese Academy of Sciences[Y609JK1001] ; Innovation R&D Team of Dongguan City[2014607117] |
| WOS研究方向 | Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000440287100041 |
| 出版者 | SPRINGER |
| 资助机构 | Natural Science Foundation of Guangdong Province ; National Natural Science Foundation of China ; Key Lab of Renewable Energy Foundation of Chinese Academy of Sciences ; Innovation R&D Team of Dongguan City |
| 源URL | [http://ir.giec.ac.cn/handle/344007/23688]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Yan, Changfeng |
| 作者单位 | 1.Chinese Acad Sci, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 3.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China 4.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tao, Qingqing,Wang, Zhida,Jayasundera, Bandara,et al. Enhanced catalytic activity of Ni-Mo2C/La2O3-ZrO2 bifunctional catalyst for dry reforming of methane[J]. JOURNAL OF MATERIALS SCIENCE,2018,53(20):14559-14572. |
| APA | Tao, Qingqing.,Wang, Zhida.,Jayasundera, Bandara.,Guo, Changqing.,Gan, Yuan.,...&Yan, Changfeng.(2018).Enhanced catalytic activity of Ni-Mo2C/La2O3-ZrO2 bifunctional catalyst for dry reforming of methane.JOURNAL OF MATERIALS SCIENCE,53(20),14559-14572. |
| MLA | Tao, Qingqing,et al."Enhanced catalytic activity of Ni-Mo2C/La2O3-ZrO2 bifunctional catalyst for dry reforming of methane".JOURNAL OF MATERIALS SCIENCE 53.20(2018):14559-14572. |
入库方式： OAI收割
来源：广州能源研究所
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