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Direct conversion of simulated propene-rich bio-syngas to liquid iso-hydrocarbons via FT-oligomerization integrated catalytic process

文献类型：期刊论文

作者Zhang, Qian2,3,4,5; Wang, Tiejun2,3,4; Weng, Yujing2,3,4,5; Zhang, Huiyan1; Vitidsant, Tharapong6; Li, Yuping2,3,4; Zhang, Qi2,3,4; Xiao, Rui1; Wang, Chenguang2,3,4; Ma, Longlong2,3,4
刊名ENERGY CONVERSION AND MANAGEMENT
出版日期2018-09-01
卷号171页码:211-221
ISSN号0196-8904
关键词FT-Oli Biomass Bio-syngas Fischer-Tropsch synthesis (FTS) Oligomerization Isomerized hydrocarbon
DOI10.1016/j.enconman.2018.05.057
通讯作者Wang, Chenguang(wangcg@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn)
英文摘要The bio-syngas formed from the catalytic cracking of bio-oil include two types of useful components which are light olefin and H-2, CO. The integration of FTS and olefinic polymerization seems potential way for the production of hydrocarbon bio-fuels while fully utilizing the olefin-rich bio-syngas. This work aimed to develop an integrated process for the production of liquid hydrocarbons directly from the olefin-rich bio-syngas through a one-stage process, which included the synthesis of liquid hydrocarbons via the oligomerization of light olefin over HZSM-5 along with the FT (Fischer-Tropsch) synthesis of H-2, CO over FeMn catalyst. A series of integration configuration composed of Fe-based catalyst (FeMn) and acidic zeolite (HZSM-5) were investigated, it was found that the undesired hydrogenation of lower olefin on the nearby metal active site seems greatly affected the yield of C5 +. More significantly, the proximity of the two active components plays a crucial role in suppressing the undesired hydrogenation reaction and contributing to the high selectivity of liquid hydrocarbons. The optimal catalytic performance yields a high selectivity to gasoline-range hydrocarbons (87.3%) with excellent low olefin hydrogenation selectivity (7.4%). Meanwhile, the obtained gasoline-range hydrocarbon showed high degree of isomerization. The integrated transformation process potentially provides an alternative way for the production of gasoline range isomerized hydrocarbon fuels using olefin-rich bio-syngas.
WOS关键词FISCHER-TROPSCH SYNTHESIS ; AMORPHOUS SILICA-ALUMINA ; LIGHT OLEFINS ; BIFUNCTIONAL CATALYSTS ; COBALT CATALYSTS ; DIESEL FUEL ; OIL ; PERFORMANCE ; CRACKING ; BIOMASS
资助项目National Natural Science Foundation of China[51476175] ; Projects of International Cooperation and Exchanges NSFC[51561145010] ; One Hundred Person Project of the Chinese Academy of Sciences ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01N092]
WOS研究方向Thermodynamics ; Energy & Fuels ; Mechanics
语种英语
出版者PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号WOS:000442972500017
资助机构National Natural Science Foundation of China ; Projects of International Cooperation and Exchanges NSFC ; One Hundred Person Project of the Chinese Academy of Sciences ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program
源URL[http://ir.giec.ac.cn/handle/344007/23763]  
专题中国科学院广州能源研究所
通讯作者Wang, Chenguang; Ma, Longlong
作者单位1.Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Jiangsu, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Nengyuan Rd 2, Guangzhou, Guangdong, Peoples R China
3.CAS Key Lab Renewable Energy, Nengyuan Rd 2, Guangzhou, Guangdong, Peoples R China
4.Guangdong Prov Key Lab New & Renewable Energy Res, Nengyuan Rd 2, Guangzhou, Guangdong, Peoples R China
5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
6.Chulalongkorn Univ, Dept Chem Technol, Fac Sci, Bangkok 10330, Thailand
推荐引用方式
GB/T 7714		 Zhang, Qian,Wang, Tiejun,Weng, Yujing,et al. Direct conversion of simulated propene-rich bio-syngas to liquid iso-hydrocarbons via FT-oligomerization integrated catalytic process[J]. ENERGY CONVERSION AND MANAGEMENT,2018,171:211-221.
APA Zhang, Qian.,Wang, Tiejun.,Weng, Yujing.,Zhang, Huiyan.,Vitidsant, Tharapong.,...&Ma, Longlong.(2018).Direct conversion of simulated propene-rich bio-syngas to liquid iso-hydrocarbons via FT-oligomerization integrated catalytic process.ENERGY CONVERSION AND MANAGEMENT,171,211-221.
MLA Zhang, Qian,et al."Direct conversion of simulated propene-rich bio-syngas to liquid iso-hydrocarbons via FT-oligomerization integrated catalytic process".ENERGY CONVERSION AND MANAGEMENT 171(2018):211-221.

入库方式： OAI收割

来源：广州能源研究所

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