Conversion of biomass-derived carbohydrates into 5-hydroxymethylfurfural catalyzed by sulfonic acid-functionalized carbon material with high strong-acid density in gamma-valerolactone
文献类型：期刊论文
| 作者 | Huang, Feng1; Li, Wenzhi1; Zhang, Tingwei1; Li, Dawei2; Liu, Qiyu1; Zhu, Xifeng1; Ma, Longlong3
|
| 刊名 | RESEARCH ON CHEMICAL INTERMEDIATES
 |
| 出版日期 | 2018-09-01 |
| 卷号 | 44期号:9页码:5439-5453 |
| 关键词 | Carbohydrate Fructose Glucose 5-Hydroxymethylfurfural gamma-Valerolactone Carbon solid acid |
| ISSN号 | 0922-6168 |
| DOI | 10.1007/s11164-018-3432-y |
| 通讯作者 | Li, Wenzhi(liwenzhi@ustc.edu.cn) |
| 英文摘要 | A carbonaceous solid acid catalyst with high strong-acid density was synthesized by facile functionalization of a biomass-derived mesoporous carbon with benzenesulfonic acid. The catalyst was characterized by using Fourier transform infrared spectroscopy, elemental analysis, X-ray photoelectron spectroscopy, transmission electron microscopy, and N-2 adsorption-desorption. The carbonaceous solid catalyst containing Bronsted acid sites was used for the production of 5-hydroxymethylfurfural (HMF) from hexoses such as fructose, glucose, and cellulose in gamma-valerolactone (GVL)-H2O mixture. By reaction at 130 degrees C for 20 min using fructose as a feedstock, an HMF yield 78.1% was achieved. The catalytic performance of the catalyst in conversion of fructose into HMF hardly changed over seven cycles, demonstrating that the catalyst had excellent recyclability. The yields of HMF derived from glucose and cellulose reached 33.2 and 22.5%, respectively, whereas those of total furans were 42.1 and 33.7%, respectively. The proposed reaction system was promising in transforming biomass-based carbohydrates into fine chemicals, given the use of green functionalization methods, the utilization of sustainable biomass-derived carbon precursor and solvents, catalyst with high acid density, and the availability of high HMF yield. |
| WOS关键词 | IONIC LIQUID ; SELECTIVE CONVERSION ; AQUEOUS-MEDIA ; CORN STALK ; FRUCTOSE ; GLUCOSE ; DEHYDRATION ; HMF ; 5-HMF ; CELLULOSE |
| 资助项目 | State Key Program of National Natural Science Foundation of China[51536009] ; Science and Technological Fund of Anhui Province for Outstanding Youth[1508085J01] ; National Key Technology R&D Program of China[2015BAD15B06] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000441789200029 |
| 出版者 | SPRINGER |
| 资助机构 | State Key Program of National Natural Science Foundation of China ; Science and Technological Fund of Anhui Province for Outstanding Youth ; National Key Technology R&D Program of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/23769]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Li, Wenzhi |
| 作者单位 | 1.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 230026, Anhui, Peoples R China 2.China Univ Petr East China, State Key Lab Heavy Oil Proc, Qingdao 266580, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Feng,Li, Wenzhi,Zhang, Tingwei,et al. Conversion of biomass-derived carbohydrates into 5-hydroxymethylfurfural catalyzed by sulfonic acid-functionalized carbon material with high strong-acid density in gamma-valerolactone[J]. RESEARCH ON CHEMICAL INTERMEDIATES,2018,44(9):5439-5453. |
| APA | Huang, Feng.,Li, Wenzhi.,Zhang, Tingwei.,Li, Dawei.,Liu, Qiyu.,...&Ma, Longlong.(2018).Conversion of biomass-derived carbohydrates into 5-hydroxymethylfurfural catalyzed by sulfonic acid-functionalized carbon material with high strong-acid density in gamma-valerolactone.RESEARCH ON CHEMICAL INTERMEDIATES,44(9),5439-5453. |
| MLA | Huang, Feng,et al."Conversion of biomass-derived carbohydrates into 5-hydroxymethylfurfural catalyzed by sulfonic acid-functionalized carbon material with high strong-acid density in gamma-valerolactone".RESEARCH ON CHEMICAL INTERMEDIATES 44.9(2018):5439-5453. |
入库方式： OAI收割
来源：广州能源研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。