中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Biodiesel production by a highly effective renewable catalyst from pyrolytic rice husk

文献类型:期刊论文

作者Zhao, Che1,2,3,4; Yang, Lingmei2,3,4; Xing, Shiyou2,3,4; Luo, Wen2,3,4; Wang, Zhongming2,3,4; Lv, Pengmei2,3,4,5
刊名JOURNAL OF CLEANER PRODUCTION
出版日期2018-10-20
卷号199页码:772-780
关键词Transesterification Biodiesel CaO-SiO2 Biochar Rice husk
ISSN号0959-6526
DOI10.1016/j.jclepro.2018.07.242
通讯作者Lv, Pengmei(lvpm@ms.giec.ac.cn)
英文摘要High efficiency and stable CaO-based catalysts which used rice husk biochar as a carrier were utilized to catalyze transesterification of vegetable oil with methanol. The properties of the synthesized catalyst were determined using XRD, TGA, Ff-IR, SEM, EDX, N-2 adsorption/desorption, XPS and the Hammett indicator method. The influences of catalyst preparation, reaction parameters and reusability of catalyst were also investigated. The results indicated that the catalyst activity mainly depended on the pretreatment temperature, structure and basicity of the catalysts. The maximum yield could reach 93.4% under the prepared conditions of 30% CaO loading and 700 degrees C calcination temperature. Meanwhile, after being reused for 10 cycles, there was no noticeable loss of catalyst activity in biodiesel yield (above 85%). The appearance of Ca-O-Si bond on the catalyst surface was the main reason for high stability. The findings suggested that the rice husk biochar based catalyst was a very promising choice for biodiesel production. (C) 2018 Elsevier Ltd. All rights reserved.
WOS关键词SOLID BASE CATALYST ; WASTE COOKING OIL ; PALM OIL ; VEGETABLE-OIL ; SOYBEAN OIL ; HETEROGENEOUS CATALYST ; CALCIUM-OXIDE ; SEWAGE-SLUDGE ; CAO CATALYST ; FLY-ASH
资助项目National Natural Science Foundation of China[51606201] ; National Natural Science Foundation of China[21576260] ; Natural Science Foundation of Guangdong Province[2016A030308004] ; Natural Science Foundation of Guangdong Province[2015A030313720] ; Special Funds of Applied Science and Technology Research of Guangdong Province[2015B020241002]
WOS研究方向Science & Technology - Other Topics ; Engineering ; Environmental Sciences & Ecology
语种英语
WOS记录号WOS:000444358400070
出版者ELSEVIER SCI LTD
资助机构National Natural Science Foundation of China ; Natural Science Foundation of Guangdong Province ; Special Funds of Applied Science and Technology Research of Guangdong Province
源URL[http://ir.giec.ac.cn/handle/344007/23879]  
专题中国科学院广州能源研究所
通讯作者Lv, Pengmei
作者单位1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
3.CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
4.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China
5.Collaborat Innovat Ctr Biomass Energy, Zhengzhou 450002, Henan, Peoples R China
推荐引用方式
GB/T 7714
Zhao, Che,Yang, Lingmei,Xing, Shiyou,et al. Biodiesel production by a highly effective renewable catalyst from pyrolytic rice husk[J]. JOURNAL OF CLEANER PRODUCTION,2018,199:772-780.
APA Zhao, Che,Yang, Lingmei,Xing, Shiyou,Luo, Wen,Wang, Zhongming,&Lv, Pengmei.(2018).Biodiesel production by a highly effective renewable catalyst from pyrolytic rice husk.JOURNAL OF CLEANER PRODUCTION,199,772-780.
MLA Zhao, Che,et al."Biodiesel production by a highly effective renewable catalyst from pyrolytic rice husk".JOURNAL OF CLEANER PRODUCTION 199(2018):772-780.

入库方式: OAI收割

来源:广州能源研究所

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