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Hydrodeoxygenation of lignin-derived phenoic compounds to hydrocarbon fuel over supported Ni-based catalysts

文献类型：期刊论文

作者Zhang, Xinghua1; Tang, Wenwu; Zhang, Qi; Wang, Tiejun; Ma, Longlong1
刊名APPLIED ENERGY
出版日期2018-10-01
卷号227页码:73-79
关键词Lignin Phenolic compounds Hydrodeoxygenation Ni/SiO2 Hydrocarbon
ISSN号0306-2619
DOI10.1016/j.apenergy.2017.08.078
通讯作者Zhang, Xinghua(zhangxh@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn)
英文摘要Ni-based catalysts supported on gamma-Al2O3 and SiO2 were prepared by impregnation. Catalyst characterization was performed using XRD, NH3-TPD,H-2-TPR and chemisorption. Effects of supports on catalytic performance were tested using the hydrodeoxygenation (HDO) of phenolic compounds as a model reaction. Experiment result shows that single phenolic compounds can be converted via HDO reaction over Ni/SiO2 and Ni/gamma-Al2O3 catalysts at 300 degrees C. The hydrocarbon yields are in the range of 60-90%. The effect of supports on the reaction mechanism was also explored. It is found that hydrogenation of the aromatic ring preferentially occurs over Ni/SiO2 catalyst while the cleavage of C-AR-O bond preferentially occurs over Ni/gamma-Al2O3 catalyst in the HDO of phenol. Compared to Ni/gamma-Al2O3 catalyst, Ni/SiO2 catalyst exhibits better repeatability and higher catalytic activity for hydrocarbon yield when mixed phenolic compounds were used as feedstock in the HDO reaction, and the carbon deposited on the surface of Ni/SiO2 catalyst is lower.
WOS关键词BIO-OIL ; BIOMASS ; GUAIACOL ; HYDROGENATION ; DECOMPOSITION ; DEGRADATION ; TEMPERATURE ; CHEMICALS ; GASOLINE ; PT/SIO2
资助项目National Natural Science Foundation of China - China[51536009] ; National Natural Science Foundation of China - China[51576198] ; National Key Technology R & D Program - China[2015BAD15B06] ; STS program of Chinese Academy of Sciences - China[KFJ-EW-STS-138] ; Science and Technology Planning Project of Guangdong Province - China[2014A01016020] ; Youth Innovation Promotion Association of Chinese Academy of Sciences - China[2015288]
WOS研究方向Energy & Fuels ; Engineering
语种英语
WOS记录号WOS:000445987200008
出版者ELSEVIER SCI LTD
资助机构National Natural Science Foundation of China - China ; National Key Technology R & D Program - China ; STS program of Chinese Academy of Sciences - China ; Science and Technology Planning Project of Guangdong Province - China ; Youth Innovation Promotion Association of Chinese Academy of Sciences - China
源URL[http://ir.giec.ac.cn/handle/344007/24006]  
专题中国科学院广州能源研究所
通讯作者Zhang, Xinghua; Ma, Longlong
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
2.CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式
GB/T 7714		 Zhang, Xinghua,Tang, Wenwu,Zhang, Qi,et al. Hydrodeoxygenation of lignin-derived phenoic compounds to hydrocarbon fuel over supported Ni-based catalysts[J]. APPLIED ENERGY,2018,227:73-79.
APA Zhang, Xinghua,Tang, Wenwu,Zhang, Qi,Wang, Tiejun,&Ma, Longlong.(2018).Hydrodeoxygenation of lignin-derived phenoic compounds to hydrocarbon fuel over supported Ni-based catalysts.APPLIED ENERGY,227,73-79.
MLA Zhang, Xinghua,et al."Hydrodeoxygenation of lignin-derived phenoic compounds to hydrocarbon fuel over supported Ni-based catalysts".APPLIED ENERGY 227(2018):73-79.

入库方式： OAI收割

来源：广州能源研究所

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