Production of HMF from glucose using an Al3+-promoted acidic phenol-formaldehyde resin catalyst
文献类型：期刊论文
| 作者 | Zhang, Tingwei1; Li, Wenzhi1; Xin, Haosheng2; Jin, Lele1; Liu, Qiying2
|
| 刊名 | CATALYSIS COMMUNICATIONS
 |
| 出版日期 | 2019-05-05 |
| 卷号 | 124页码:56-61 |
| 关键词 | Al-SPFR Glucose HMF GVL/H20 Heterogeneous catalysis |
| ISSN号 | 1566-7367 |
| DOI | 10.1016/j.catcom.2019.03.001 |
| 通讯作者 | Li, Wenzhi(liwenzhi@ustc.edu.cn) |
| 英文摘要 | An Al3+-modified formaldehyde-p-hydroxybenzenesulfonic acid resin catalyst (Al-SPFR) was synthesized through a hydrothermal method. N-2 adsorption-desorption experiment and acid-base titration revealed that the Al-SPFR catalyst had better texture properties and higher strong acid content than the previously prepared unmodified SPFR. The effects of reaction time and temperature, catalyst loading, and water content in water/GVL mixture were investigated for glucose dehydration using Al-SPFR as the catalyst. An HMF yield of 47.4% was obtained at 170 degrees C for 2 h in the biphasic GVL/H2O medium. Further performing a five-cycle experiment, the HMF yield initially decreased and then remained fairly constant, and the recyclability of the Al-SPFR was reasonable. |
| WOS关键词 | LIGNOCELLULOSIC BIOMASS ; MOLECULAR-STRUCTURE ; IONIC LIQUIDS ; CORN STOVER ; LEWIS-ACID ; CONVERSION ; MORPHOLOGY ; TRANSFORMATION ; CELLULOSE ; FRUCTOSE |
| 资助项目 | Science and Technological Fund of Anhui Province for Outstanding Youth[1508085J01] ; International Technology Cooperation Plan of Anhui[1503062030] ; National Key Technology R&D Program of China[2015BAD15B06] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000464482500011 |
| 出版者 | ELSEVIER SCIENCE BV |
| 资助机构 | Science and Technological Fund of Anhui Province for Outstanding Youth ; International Technology Cooperation Plan of Anhui ; National Key Technology R&D Program of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/24828]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Li, Wenzhi |
| 作者单位 | 1.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 230026, Anhui, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Tingwei,Li, Wenzhi,Xin, Haosheng,et al. Production of HMF from glucose using an Al3+-promoted acidic phenol-formaldehyde resin catalyst[J]. CATALYSIS COMMUNICATIONS,2019,124:56-61. |
| APA | Zhang, Tingwei,Li, Wenzhi,Xin, Haosheng,Jin, Lele,&Liu, Qiying.(2019).Production of HMF from glucose using an Al3+-promoted acidic phenol-formaldehyde resin catalyst.CATALYSIS COMMUNICATIONS,124,56-61. |
| MLA | Zhang, Tingwei,et al."Production of HMF from glucose using an Al3+-promoted acidic phenol-formaldehyde resin catalyst".CATALYSIS COMMUNICATIONS 124(2019):56-61. |
入库方式： OAI收割
来源：广州能源研究所
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