Screening Solvents Based on Hansen Solubility Parameter Theory To Depolymerize Lignocellulosic Biomass Efficiently under Low Temperature
文献类型：期刊论文
| 作者 | Zhang, Quan1,2,3,4; Tan, Xuesong1,2,3 ; Wang, Wen1,2,3; Yu, Qiang1,2,3; Wang, Qiong1,2,3; Miao, Changlin1,2,3; Guo, Ying1,2,3; Zhuang, Xinshu1,2,3; Yuan, Zhenhong1,2,3,5
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| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
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| 出版日期 | 2019-05-06 |
| 卷号 | 7期号:9页码:8678-8686 |
| 关键词 | Hansen solubility parameter Organic solvents Pretreatment Delignification Enzymatic hydrolysis |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.9b00494 |
| 通讯作者 | Tan, Xuesong(tanxs@ms.giec.ac.cn) ; Zhuang, Xinshu(zhuangxs@ms.giec.ac.cn) |
| 英文摘要 | Ten solvents including water-soluble and water-insoluble solvents were first used to pretreat rice straw under facile conditions (110 degrees C, 60 min). The results showed that most of the hemicellulose was removed, and much of the cellulose was held in solid residue. On the basis of the Hansen solubility parameter (HSP) theory, the correlation between the relative energy difference of the solvent-system-lignin interactions and the lignin removal was explored. Taking efficient enzymatic hydrolysis and ease fractionation of lignocellulosic biomass into account, biphase solvent 2-phenoxyethanol (KL-EPH) was selected for further study. After that, the effects of temperature, retention time, sulfuric acid loading, and KL-EPH concentration on the degradation of rice straw were studied, and the results indicated that the conditions of temperature 120 degrees C, retention time 3 h, sulfuric acid loading 0.1 M, and KL-EPH concentration 50% were optimal. Under these conditions, 90.17% of hemicellulose and 53.17% of lignin were removed from rice straw, resulting in the residue enzymatic hydrolysis rate of 88%, and 66% of hemicellulose as xylose was present in the aqueous phase. Moreover, 33.55% of the precipitated solid (lignin rich) was collected from the organic phase. The componential analysis suggested the lignin-rich residue mainly consisted of 78.68% lignin, 8.26% glucan, and 1.65% xylan. The raw materials and residues were characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, and X-ray diffraction, and the results showed that the remarkable removal of hemicellulose and lignin primarily contributed to the improved enzymatic hydrolysis of the residue based on these results. |
| WOS关键词 | ORGANOSOLV PRETREATMENT ; IONIC LIQUIDS ; WHEAT-STRAW ; ENZYMATIC-HYDROLYSIS ; ETHANOL-PRODUCTION ; LIGNIN ; FRACTIONATION ; CELLULOSE ; DELIGNIFICATION ; CONVERSION |
| 资助项目 | National Key Research and Development Program of China[2018YFB1501402] ; National Natural Science Foundation of China[51876206] ; National Natural Science Foundation of China[51606203] ; National Natural Science Foundation of China[51476179] ; Pearl River S&T Nova Program of Guangzhou, China[201806010052] ; Open Fund of Guangdong Key Laboratory for Innovative Development and Utilization of Forest Plant Germplasm, South China Agricultural University |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000467351200071 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Key Research and Development Program of China ; National Natural Science Foundation of China ; Pearl River S&T Nova Program of Guangzhou, China ; Open Fund of Guangdong Key Laboratory for Innovative Development and Utilization of Forest Plant Germplasm, South China Agricultural University |
| 源URL | [http://ir.giec.ac.cn/handle/344007/25012]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Tan, Xuesong; Zhuang, Xinshu |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 501640, Guangdong, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou 501640, Guangdong, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 501640, Guangdong, Peoples R China 4.Univ Chinese Acad Sci, Beijing 10049, Peoples R China 5.Collaborat Innovat Ctr Biomass Energy, Zhengzhou 450002, Henan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Quan,Tan, Xuesong,Wang, Wen,et al. Screening Solvents Based on Hansen Solubility Parameter Theory To Depolymerize Lignocellulosic Biomass Efficiently under Low Temperature[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2019,7(9):8678-8686. |
| APA | Zhang, Quan.,Tan, Xuesong.,Wang, Wen.,Yu, Qiang.,Wang, Qiong.,...&Yuan, Zhenhong.(2019).Screening Solvents Based on Hansen Solubility Parameter Theory To Depolymerize Lignocellulosic Biomass Efficiently under Low Temperature.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,7(9),8678-8686. |
| MLA | Zhang, Quan,et al."Screening Solvents Based on Hansen Solubility Parameter Theory To Depolymerize Lignocellulosic Biomass Efficiently under Low Temperature".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 7.9(2019):8678-8686. |
入库方式： OAI收割
来源：广州能源研究所
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