Synthesis and Configurational Character Study of Novel Structural Isomers Based on Pyrene-Imidazole
文献类型：期刊论文
| 作者 | Liu, Yu-Long1,2; Yang, Liu2; Guo, You-Quan3; Xu, Guo-Qiang2; Qu, Bin1,2; Fu, Ying2 |
| 刊名 | MOLECULES
 |
| 出版日期 | 2019-06-02 |
| 卷号 | 24期号:12页码:11 |
| 关键词 | one-pot reaction pyrene-imidazole structural isomer molecular symmetry crystal structure |
| ISSN号 | 1420-3049 |
| DOI | 10.3390/molecules24122293 |
| 通讯作者 | Fu, Ying(fuying@neau.edu.cn) |
| 英文摘要 | Isomers provide more possibilities for the structure of organic compounds. Molecular structures determine their corresponding properties, therefore the intrinsic relationship between structure and properties of isomers is of great research value. Isomers with a stable structure and excellent performance possess more potential for development and application. In this paper, we design and synthesize structural isomers with different molecular symmetries based on the asymmetric structure of imidazole and the symmetrical structure of pyrene. Isomers with stable molecular structures can be obtained by a simple and efficient one-pot reaction, involving axisymmetric configuration and centrosymmetric configuration. Using this click-like reaction, the structure of target molecules is controllable and adjustable. Furthermore, the effect of molecular configurations on molecular stacking of crystal is studied. The variation of the optical and thermal properties, the optimized structures, and orbital distributions of isomers depends on different molecular geometry with different symmetry, which are revealed by crystallographic analysis. This present strategy provides an efficient synthetic method for the design and synthesis of structural isomers based on pyrene-imidazole. |
| WOS关键词 | ISOMERICALLY PURE ; HIGHLY EFFICIENT ; DEEP-BLUE ; FLUORESCENCE ; PERFORMANCE ; DERIVATIVES ; CRYSTAL ; PACKING ; CONFORMATION |
| 资助项目 | Natural Science Foundation of Heilongjiang Province[LH2019B002] ; Postdoctoral Science Foundation of Heilongjiang Province[LBH-Z17014] ; CAS Key Laboratory of Renewable Energy[Y907k71001] |
| WOS研究方向 | Biochemistry & Molecular Biology ; Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000473816900099 |
| 出版者 | MDPI |
| 资助机构 | Natural Science Foundation of Heilongjiang Province ; Postdoctoral Science Foundation of Heilongjiang Province ; CAS Key Laboratory of Renewable Energy |
| 源URL | [http://ir.giec.ac.cn/handle/344007/25278]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Fu, Ying |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Northeast Agr Univ, Coll Sci, Dept Appl Chem, Harbin 150030, Heilongjiang, Peoples R China 3.Heilongjiang Vocat Coll Biol Sci & Technol, Harbin 150025, Heilongjiang, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Yu-Long,Yang, Liu,Guo, You-Quan,et al. Synthesis and Configurational Character Study of Novel Structural Isomers Based on Pyrene-Imidazole[J]. MOLECULES,2019,24(12):11. |
| APA | Liu, Yu-Long,Yang, Liu,Guo, You-Quan,Xu, Guo-Qiang,Qu, Bin,&Fu, Ying.(2019).Synthesis and Configurational Character Study of Novel Structural Isomers Based on Pyrene-Imidazole.MOLECULES,24(12),11. |
| MLA | Liu, Yu-Long,et al."Synthesis and Configurational Character Study of Novel Structural Isomers Based on Pyrene-Imidazole".MOLECULES 24.12(2019):11. |
入库方式： OAI收割
来源：广州能源研究所
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