Low-Temperature Synthesis of Highly Efficient, Deep-Red Zn-Cu-In-Se/ZnSe Fluorescence Quantum Dots
文献类型：期刊论文
| 作者 | Yang, Juan2,3; Li, Jingling1,2; Zhu, Yanqing1,2 ; Xu, Xueqing1,2; Xiao, Xiudi1,2; Deng, Bing1,2; Qin, Kaili2,3; Bi, Zhuoneng1,2; Chen, Shuaijun4; Xu, Gang1,2
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| 刊名 | NANO
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| 出版日期 | 2019-06-01 |
| 卷号 | 14期号:6页码:10 |
| 关键词 | Quantum dots deep-red ZnCuInSe ZuCuInSe/ZnSe low-temperature synthesis |
| ISSN号 | 1793-2920 |
| DOI | 10.1142/S179329201950070X |
| 通讯作者 | Yang, Juan(yangjuan@ms.giec.ac.in) |
| 英文摘要 | We report a facile synthesis method on CuInSe2 (CISe)-based quantum dots (QDs) by using tri-n-octylphosphine selenium (TOPSe) as selenide precursor, with assistance of oleylamine (OAm) and n-dodecanethiol (DDT). We demonstrate that the OAm and DDT jointly contribute to the formation of the low-temperature-decomposable metal-sulfide clusters, and promote the QD nucleation at relatively low temperature range of 180-200 degrees C. Furthermore, to improve fluorescence property, Zn-doping and ZnSe coating are simultaneously carried out. The obtained deep-red ZnCISe/ZnSe QDs possess higher quantum yield of 65% at wavelength of 670 nm, which is in the best performance range ever reported. Then, we investigate the improvement mechanism, where the sufficient Zn replacement of In sites is the crucial factor. This modified core-shell structure provides two benefits, on the one hand, the enhancement on intrinsic defect-related recombination, and the other hand, the improved core-shell interface that reduces the nonradiative recombination. |
| WOS关键词 | LIGHT-EMITTING-DIODES ; CUINS2 NANOCRYSTALS ; OPTICAL-PROPERTIES ; LUMINESCENT ; QUALITY ; STATE |
| 资助项目 | Key Project on Synergy Collaborative Innovation of Guangzhou City[201704030069] ; Project on the Collaborative Innovation and Environmental Construction Platform of Guangdong Province[2018A050506067] ; National Key R&D Program of China[2018YFD0700200] ; Project of Science and Technology Service Network initiative, Chinese Academy of Sciences[KFJ-STS-QYZD-010] ; Major Science and Technology Project of Tibet Autonomous Region[ZD20170017] ; Youth Innovation Promotion Association CAS[2017400] ; Special Plan of Guangdong Province[2015TQ01N714] ; Natural Science Foundation of Guangdong Province[2018A0303130146] |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000473366900005 |
| 出版者 | WORLD SCIENTIFIC PUBL CO PTE LTD |
| 资助机构 | Key Project on Synergy Collaborative Innovation of Guangzhou City ; Project on the Collaborative Innovation and Environmental Construction Platform of Guangdong Province ; National Key R&D Program of China ; Project of Science and Technology Service Network initiative, Chinese Academy of Sciences ; Major Science and Technology Project of Tibet Autonomous Region ; Youth Innovation Promotion Association CAS ; Special Plan of Guangdong Province ; Natural Science Foundation of Guangdong Province |
| 源URL | [http://ir.giec.ac.cn/handle/344007/25390]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Yang, Juan |
| 作者单位 | 1.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China 4.Southern Med Univ, Zhujiang Hosp, Dept Otolaryngol Head & Neck Surg, Guangzhou 510282, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Juan,Li, Jingling,Zhu, Yanqing,et al. Low-Temperature Synthesis of Highly Efficient, Deep-Red Zn-Cu-In-Se/ZnSe Fluorescence Quantum Dots[J]. NANO,2019,14(6):10. |
| APA | Yang, Juan.,Li, Jingling.,Zhu, Yanqing.,Xu, Xueqing.,Xiao, Xiudi.,...&Xu, Gang.(2019).Low-Temperature Synthesis of Highly Efficient, Deep-Red Zn-Cu-In-Se/ZnSe Fluorescence Quantum Dots.NANO,14(6),10. |
| MLA | Yang, Juan,et al."Low-Temperature Synthesis of Highly Efficient, Deep-Red Zn-Cu-In-Se/ZnSe Fluorescence Quantum Dots".NANO 14.6(2019):10. |
入库方式： OAI收割
来源：广州能源研究所
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