Biomass-Tar-Enabled Nitrogen-Doped Highly Ultramicroporous Carbon as an Efficient Absorbent for CO2 Capture
文献类型：期刊论文
| 作者 | Li, Denian1,2; Chen, Jian1,2 ; Fan, Yukun1,2,4; Deng, Lifang1,2; Shan, Rui1,2; Chen, Huibing1,2; Yuan, Haoran1,2,3; Chen, Yong1,2,3,4
|
| 刊名 | ENERGY & FUELS
 |
| 出版日期 | 2019-09-01 |
| 卷号 | 33期号:9页码:8927-8936 |
| ISSN号 | 0887-0624 |
| DOI | 10.1021/acs.energyfuels.9b01638 |
| 通讯作者 | Yuan, Haoran(yuanhr@ms.giec.ac.cn) |
| 英文摘要 | As a notorious hazardous waste, biomass tar has for a long time been recognized as one of the key challenges throughout the progress in biomass gasification for renewable energy and chemical purposes. In this contribution, we report that biomass tar featured with considerably high carbon and nitrogen contents could serve as an ideal source for production of nitrogen-doped highly ultramicroporous carbon following the facile activation approach, which enabled a remarkably high ultramicroporosity based on a direct bottom-up strategy. Further, the disclosed evenly distributed active sites by nitrogen-doped ultramicropores displayed excellent CO2 absorption capacity as high as 6.02 and 4.11 mmol/g (1 bar) at 273 and 298 K, respectively, in addition to the corresponding ideal adsorption solvent theory selectivity of 30 and 24, which are all among the highest level of solid CO2 absorbents developed thus far. This work may inspire new sparks on rational disposal of tar-like byproducts from pyrolysis of organic solid waste and also encourage future utilization of them for advanced materials for innovative environmental applications, including CO2 capture and storage and gaseous pollution control, among others. |
| WOS关键词 | POROUS ORGANIC POLYMERS ; CROSS-LINKED POLYMERS ; OXYGEN REDUCTION ; DIOXIDE CAPTURE ; LOW-TEMPERATURE ; ADSORPTION ; SELECTIVITY ; ACTIVATION ; CAPACITY ; STORAGE |
| 资助项目 | National Key R&D Program of China[2018YFC1901204] ; National Natural Science Foundation of China[51806226] ; National Natural Science Foundation of China[51676194] ; Frontier Key Projects of Chinese Academy of Sciences[QYZDY-SSW-JSC038] ; Science and Technology Project of Guangdong Province[2017B040404009] |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000487178700096 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China ; Frontier Key Projects of Chinese Academy of Sciences ; Science and Technology Project of Guangdong Province |
| 源URL | [http://ir.giec.ac.cn/handle/344007/25652]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Yuan, Haoran |
| 作者单位 | 1.Chinese Acad Sci, CAS Key Lab Renewable Energy, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China 3.Changzhou Univ, Sch Petrochem Engn, Inst Urban & Rural Min, Changzhou 213164, Jiangsu, Peoples R China 4.Guangdong Univ Technol, Sch Mat & Energy, Guangzhou 510006, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Denian,Chen, Jian,Fan, Yukun,et al. Biomass-Tar-Enabled Nitrogen-Doped Highly Ultramicroporous Carbon as an Efficient Absorbent for CO2 Capture[J]. ENERGY & FUELS,2019,33(9):8927-8936. |
| APA | Li, Denian.,Chen, Jian.,Fan, Yukun.,Deng, Lifang.,Shan, Rui.,...&Chen, Yong.(2019).Biomass-Tar-Enabled Nitrogen-Doped Highly Ultramicroporous Carbon as an Efficient Absorbent for CO2 Capture.ENERGY & FUELS,33(9),8927-8936. |
| MLA | Li, Denian,et al."Biomass-Tar-Enabled Nitrogen-Doped Highly Ultramicroporous Carbon as an Efficient Absorbent for CO2 Capture".ENERGY & FUELS 33.9(2019):8927-8936. |
入库方式： OAI收割
来源：广州能源研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。