Highly selective conversion of natural oil to alcohols or alkanes over a Pd stabilized CuZnAl catalyst under mild conditions
文献类型：期刊论文
| 作者 | Guo, Ziwei1; Zhou, Feng2; Wang, Hao1; Liu, Xiaohao3; Xu, Guangyue1; Zhang, Ying1; Fu, Yao1 |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2019-09-21 |
| 卷号 | 21期号:18页码:5046-5052 |
| ISSN号 | 1463-9262 |
| DOI | 10.1039/c9gc02379h |
| 通讯作者 | Zhang, Ying(zhzhying@ustc.edu.cn) |
| 英文摘要 | A novel and green catalytic system based on a Pd stabilized CuZnAl catalyst was designed for one-pot conversion of natural oil components to the corresponding alcohols or long-chain linear and branched alkanes with high selectivity and atom economy. When methyl decanoate was used as the model compound, a nearly full yield of n-decanol was obtained at 200 degrees C and 2 MPa H-2 within 8 h. 100% decane was produced when acidic HZSM-5 was introduced under the same reaction conditions, and the selectivity of n-decane and i-decane could be tuned by temperature. Cu species were verified as the active sites for lipid conversion, while a small amount of Pd could stabilize the catalyst to avoid Cu leaching. The reaction pathway involved hydrogenation, where methyl decanoate can be equivalently converted to methanol and decanol or decane, and no extra CO2 or CO from decarboxylation or decarbonylation was detected. This system increases the sustainability and economy of natural oil conversion to valuable liquid fuel and chemicals. |
| WOS关键词 | IN-SITU HYDROGENATION ; VEGETABLE-OILS ; FATTY-ACIDS ; OLEIC-ACID ; DEOXYGENATION ; EFFICIENT ; METHANOL ; NICKEL ; DIESEL ; FUELS |
| 资助项目 | NSFC[51876200] ; NSFC[21572213] ; DNL Cooperation Fund, CAS[DNL180301] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics |
| 语种 | 英语 |
| WOS记录号 | WOS:000486309300019 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | NSFC ; DNL Cooperation Fund, CAS |
| 源URL | [http://ir.giec.ac.cn/handle/344007/25670]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Zhang, Ying |
| 作者单位 | 1.Univ Sci & Technol China, Dept Appl Chem, CAS Key Lab Urban Pollutant Convers, Hefei 230026, Anhui, Peoples R China 2.SINOPEC, Fushun Res Inst Petr & Petrochem, Fushun 113001, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangdong Key Lab New & Renewable Energy Res & De, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Ziwei,Zhou, Feng,Wang, Hao,et al. Highly selective conversion of natural oil to alcohols or alkanes over a Pd stabilized CuZnAl catalyst under mild conditions[J]. GREEN CHEMISTRY,2019,21(18):5046-5052. |
| APA | Guo, Ziwei.,Zhou, Feng.,Wang, Hao.,Liu, Xiaohao.,Xu, Guangyue.,...&Fu, Yao.(2019).Highly selective conversion of natural oil to alcohols or alkanes over a Pd stabilized CuZnAl catalyst under mild conditions.GREEN CHEMISTRY,21(18),5046-5052. |
| MLA | Guo, Ziwei,et al."Highly selective conversion of natural oil to alcohols or alkanes over a Pd stabilized CuZnAl catalyst under mild conditions".GREEN CHEMISTRY 21.18(2019):5046-5052. |
入库方式： OAI收割
来源：广州能源研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。