Catalytic conversion of cellulose to C-5/C-6 alkanes over Ir-VOx/SO2 combined with HZSM-5 in n-dodecane/water system
文献类型：期刊论文
| 作者 | Jin, Lele1,2; Li, Wenzhi1; Liu, Qiying2 ; Ma, Longlong2; Li, Song2; Liu, Yang1,2; Zhang, Baikai1; Zhang, Qi2
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| 刊名 | FUEL PROCESSING TECHNOLOGY
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| 出版日期 | 2019-12-15 |
| 卷号 | 196页码:10 |
| ISSN号 | 0378-3820 |
| 关键词 | Liquid fuel Microcrystalline cellulose Hydrogenolysis |
| DOI | 10.1016/j.fuproc.2019.106161 |
| 通讯作者 | Li, Wenzhi(liwenzhi@ustc.edu.cn) ; Zhang, Qi(zhangqi@ms.giec.ac.cn) |
| 英文摘要 | The liquid fuel (made of C-5/C-6 alkanes) was obtained directly from the hydrogenolysis of microcrystalline cellulose (MCC) with Ir-VOx/SiO2 combined with HZSM-5 as the composite catalyst in a biphasic system (n-dodecane + H2O). The performance of the catalyst was investigated by carrying out a series of experiments using various V/Ir molar ratios, catalyst dosages, reaction temperatures, reaction time, hydrogen pressure and substrates. At the optimized conditions, the cellulose was almost completely converted, and at the same time, a high C-5/C-6 yield of 85.1% was obtained at 210 degrees C for 24 h and 6 MPa with the V/Ir molar ratio being 0.13. These results not only proved that Ir-VOx/SiO2 (V/Ir = 0.13) has excellent performance for the hydrogenolysis of MCC to liquid alkanes, but also indicated that vanadium is a good metal promoter for iridium. In addition, it was proven the C-5/C-6 alkanes were obtained via sorbitol through the combined effect of Ir-VOx/SiO2 and HZSM-5. |
| WOS关键词 | AQUEOUS-PHASE HYDROGENATION ; LIGNOCELLULOSIC BIOMASS ; TETRAHYDROFURFURYL ALCOHOL ; SELECTIVE HYDROGENATION ; LIQUEFIED FUEL ; LEVULINIC ACID ; SUGAR POLYOLS ; KRAFT LIGNIN ; CORN STOVER ; HYDROGENOLYSIS |
| 资助项目 | National Natural Science Foundation of China[51536009] ; National Key Research and Development Program of China[2018YFB1501402] ; Natural Science Foundation of Guangdong Province[2017A030308010] ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01N092] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Engineering |
| 语种 | 英语 |
| 出版者 | ELSEVIER |
| WOS记录号 | WOS:000487576700009 |
| 资助机构 | National Natural Science Foundation of China ; National Key Research and Development Program of China ; Natural Science Foundation of Guangdong Province ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program |
| 源URL | [http://ir.giec.ac.cn/handle/344007/25697]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Li, Wenzhi; Zhang, Qi |
| 作者单位 | 1.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Lab Basic Res Biomass Convers & Utilizat, Hefei 230026, Anhui, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jin, Lele,Li, Wenzhi,Liu, Qiying,et al. Catalytic conversion of cellulose to C-5/C-6 alkanes over Ir-VOx/SO2 combined with HZSM-5 in n-dodecane/water system[J]. FUEL PROCESSING TECHNOLOGY,2019,196:10. |
| APA | Jin, Lele.,Li, Wenzhi.,Liu, Qiying.,Ma, Longlong.,Li, Song.,...&Zhang, Qi.(2019).Catalytic conversion of cellulose to C-5/C-6 alkanes over Ir-VOx/SO2 combined with HZSM-5 in n-dodecane/water system.FUEL PROCESSING TECHNOLOGY,196,10. |
| MLA | Jin, Lele,et al."Catalytic conversion of cellulose to C-5/C-6 alkanes over Ir-VOx/SO2 combined with HZSM-5 in n-dodecane/water system".FUEL PROCESSING TECHNOLOGY 196(2019):10. |
入库方式： OAI收割
来源：广州能源研究所
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