Selective Hydrodeoxygenation of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran over Ni Supported on Zirconium Phosphate Catalysts
文献类型：期刊论文
| 作者 | Zhu, Changhui1,2,3,4; Liu, Qiying1,2,3 ; Li, Dan1,2,3,5; Wang, Haiyong1,2,3,5; Zhang, Caihong1,2,3,4; Cui, Chunhua1,2,3,5; Chen, Lungang1,2,3; Cai, Chiliu1,2,3; Ma, Longlong1,2,3
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| 刊名 | ACS OMEGA
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| 出版日期 | 2018-07-01 |
| 卷号 | 3期号:7页码:7407-7417 |
| ISSN号 | 2470-1343 |
| DOI | 10.1021/acsomega.8b00609 |
| 通讯作者 | Liu, Qiying(liuqy@ms.giec.ac.cn) |
| 英文摘要 | Crystal alpha-zirconium phosphate (alpha-ZrP) was prepared by a hydrothermal method and exfoliated into a layered structure by n-hexylamine (C6H13NH2). Ni-based catalyst (Ni/ZrP) was promoted by loading nickel on the layered alpha-ZrP via ion exchange. The catalyst was performed to catalyze hydrodeoxygenation of 5-hydroxymethylfurfural (HMF) to 2,5-dimethylfuran (DMF), and a 68.1% yield of DMF and 100% conversion of HMF were achieved at 240 degrees C, 5 MPa H-2, and 20 h. The DMF yield can still retain 52.8% after five cycles. The characteristics of the catalyst were investigated via N-2 adsorption-desorption, X-ray diffraction, field emission scanning electron microscopy, high-resolution transmission electron microscopy, pyridine-adsorbed Fourier transform infrared (FTIR) spectra, FTIR spectra, inductively coupled plasma mass spectrometry, and thermogravimetric analysis-mass spectrometry, as well as Raman spectroscopy. A pathway from HMF to DMF was found with MF as the intermediate product, and DMF production was preferable via the -CH2OH group hydrogenolysis of HMF over Lewis acidic sites of Ni/ZrP, which is caused by the zirconium vacant orbits. |
| WOS关键词 | AQUEOUS-PHASE HYDRODEOXYGENATION ; EFFICIENT PRODUCTION ; BIMETALLIC CATALYST ; BIOMASS ; ACID ; HYDROGENATION ; FRUCTOSE ; GASOLINE ; DIMETHYLFURAN ; DEHYDRATION |
| 资助项目 | National Natural Science Foundation of China[51576199] ; National Natural Science Foundation of China[51536009] ; Natural Science Foundation of Guangdong Province[2017A030308010] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000438908600030 |
| 资助机构 | National Natural Science Foundation of China ; Natural Science Foundation of Guangdong Province |
| 源URL | [http://ir.giec.ac.cn/handle/344007/25763]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Liu, Qiying |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Key Lab New & Renewable Energy Res & De, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China 4.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China 5.Univ Sci & Technol China, Sch Nano Sci & Technol, 166 Renai Rd,Suzhou Ind Pk, Suzhou 215123, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Changhui,Liu, Qiying,Li, Dan,et al. Selective Hydrodeoxygenation of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran over Ni Supported on Zirconium Phosphate Catalysts[J]. ACS OMEGA,2018,3(7):7407-7417. |
| APA | Zhu, Changhui.,Liu, Qiying.,Li, Dan.,Wang, Haiyong.,Zhang, Caihong.,...&Ma, Longlong.(2018).Selective Hydrodeoxygenation of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran over Ni Supported on Zirconium Phosphate Catalysts.ACS OMEGA,3(7),7407-7417. |
| MLA | Zhu, Changhui,et al."Selective Hydrodeoxygenation of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran over Ni Supported on Zirconium Phosphate Catalysts".ACS OMEGA 3.7(2018):7407-7417. |
入库方式： OAI收割
来源：广州能源研究所
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