Kinetic compensation effect in logistic distributed activation energy model for lignocellulosic biomass pyrolysis
文献类型：期刊论文
| 作者 | Xu, Di1; Chai, Meiyun1; Dong, Zhujun1; Rahman, Md Maksudur1; Yu, Xi3; Cai, Junmeng1,2 |
| 刊名 | BIORESOURCE TECHNOLOGY
 |
| 出版日期 | 2018-10-01 |
| 卷号 | 265页码:139-145 |
| 关键词 | Logistic distribution Distributed activation energy model (DAEM) Kinetic compensation effect Biomass pyrolysis Pattern search method |
| ISSN号 | 0960-8524 |
| DOI | 10.1016/j.biortech.2018.05.092 |
| 通讯作者 | Cai, Junmeng(jmcai@sjtu.edu.cn) |
| 英文摘要 | The kinetic compensation effect in the logistic distributed activation energy model (DAEM) for lignocellulosic biomass pyrolysis was investigated. The sum of square error (SSE) surface tool was used to analyze two theoretically simulated logistic DAEM processes for cellulose and xylan pyrolysis. The logistic DAEM coupled with the pattern search method for parameter estimation was used to analyze the experimental data of cellulose pyrolysis. The results showed that many parameter sets of the logistic DAEM could fit the data at different heating rates very well for both simulated and experimental processes, and a perfect linear relationship between the logarithm of the frequency factor and the mean value of the activation energy distribution was found. The parameters of the logistic DAEM can be estimated by coupling the optimization method and isoconversional kinetic methods. The results would be helpful for chemical kinetic analysis using DAEM. |
| WOS关键词 | SOLID FUELS ; THERMOGRAVIMETRIC ANALYSIS ; MATHEMATICAL ORIGINS ; EXPERIMENTAL ERRORS ; PARAMETERS ; BEHAVIOR ; COAL ; DEVOLATILIZATION |
| 资助项目 | CAS Key Laboratory of Renewable Energy[Y807k91001] ; Global Challenges Research Fund (GCRF) Networking Grant ('Pyrolysis of Municipal Organic Waste for Renewable Road Construction Materials') |
| WOS研究方向 | Agriculture ; Biotechnology & Applied Microbiology ; Energy & Fuels |
| 语种 | 英语 |
| WOS记录号 | WOS:000439467300018 |
| 出版者 | ELSEVIER SCI LTD |
| 资助机构 | CAS Key Laboratory of Renewable Energy ; Global Challenges Research Fund (GCRF) Networking Grant ('Pyrolysis of Municipal Organic Waste for Renewable Road Construction Materials') |
| 源URL | [http://ir.giec.ac.cn/handle/344007/25782]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Cai, Junmeng |
| 作者单位 | 1.Shanghai Jiao Tong Univ, Sch Agr & Biol, Minist Agr, Biomass Energy Engn Res Ctr,Key Lab Urban Agr Sou, 800 Dongchuan Rd, Shanghai 200240, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Aston Univ, European Bioenergy Res Inst, Birmingham B4 7ET, W Midlands, England |
| 推荐引用方式 GB/T 7714 | Xu, Di,Chai, Meiyun,Dong, Zhujun,et al. Kinetic compensation effect in logistic distributed activation energy model for lignocellulosic biomass pyrolysis[J]. BIORESOURCE TECHNOLOGY,2018,265:139-145. |
| APA | Xu, Di,Chai, Meiyun,Dong, Zhujun,Rahman, Md Maksudur,Yu, Xi,&Cai, Junmeng.(2018).Kinetic compensation effect in logistic distributed activation energy model for lignocellulosic biomass pyrolysis.BIORESOURCE TECHNOLOGY,265,139-145. |
| MLA | Xu, Di,et al."Kinetic compensation effect in logistic distributed activation energy model for lignocellulosic biomass pyrolysis".BIORESOURCE TECHNOLOGY 265(2018):139-145. |
入库方式： OAI收割
来源：广州能源研究所
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