Highly efficient catalytic conversion of cellulose into acetol over Ni-Sn supported on nanosilica and the mechanism study
文献类型：期刊论文
| 作者 | Liu, Xiaohao1,3; Liu, Xiaodong2; Xu, Guangyue2; Zhang, Ying2; Wang, Chenguang1; Lu, Qiang4; Ma, Longlong1,3
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| 刊名 | GREEN CHEMISTRY
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| 出版日期 | 2019-10-21 |
| 卷号 | 21期号:20页码:5647-5656 |
| ISSN号 | 1463-9262 |
| DOI | 10.1039/c9gc02449b |
| 通讯作者 | Zhang, Ying(zhzhying@ustc.edu.cn) ; Ma, Longlong(mall@ms.giec.ac.cn) |
| 英文摘要 | Selective conversion of cellulose into high value-added C3 chemicals is a great challenge in biorefinery due to the complicated reaction process. In this work, 61.6% yield of acetol was obtained by one pot conversion of cellulose using Ni-Sn/SiO2 catalysts. A series of characterization methods including TEM, STEM-HAADF, EDS, AAS, XRD, XPS, H-2-TPR, Py-FTIR, and CO2-TPD were carried out to explore the structure-activity relationship. The strong basicity of the catalysts was a key factor affecting the production of acetol. In addition, catalysts with the hydrothermally stable L-acid sites and no B-acid sites inhibited side reactions and ensured efficient conversion of cellulose into small molecules. Further studies showed that the formation of the Ni3Sn4 alloy significantly promoted the acetol production, and its weak hydrogenation activity inhibited further conversion of acetol. Noninteger valence tin species (Sn delta+ and SnOx) were formed both in Ni3Sn4 and Sn/SiO2. These Sn species were the source of basic sites and the active sites for catalyzing cellulose to acetol. Under the synergistic catalysis of Sn/SiO2 and the Ni3Sn4 alloy, cellulose was efficiently converted into acetol. This work provides guidance for the selective conversion of cellulose into C3 products. |
| WOS关键词 | ETHYLENE-GLYCOL ; TRANSFORMATION ; BIOMASS ; CHEMICALS ; ACID ; TIN ; HYDROXYACETONE ; DEHYDRATION ; GLYCEROL ; ETHANOL |
| 资助项目 | National Natural Science Foundation of China[51536009] ; National Natural Science Foundation of China[51876200] ; National Key R&D Program of China[2018 YFB1501402] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics |
| 语种 | 英语 |
| WOS记录号 | WOS:000490291800018 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | National Natural Science Foundation of China ; National Key R&D Program of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/25818]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Zhang, Ying; Ma, Longlong |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangdong Key Lab New & Renewable Energy Res & De, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.North China Elect Power Univ, Natl Engn Lab Biomass Power Generat Equipment, Beijing 102206, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Xiaohao,Liu, Xiaodong,Xu, Guangyue,et al. Highly efficient catalytic conversion of cellulose into acetol over Ni-Sn supported on nanosilica and the mechanism study[J]. GREEN CHEMISTRY,2019,21(20):5647-5656. |
| APA | Liu, Xiaohao.,Liu, Xiaodong.,Xu, Guangyue.,Zhang, Ying.,Wang, Chenguang.,...&Ma, Longlong.(2019).Highly efficient catalytic conversion of cellulose into acetol over Ni-Sn supported on nanosilica and the mechanism study.GREEN CHEMISTRY,21(20),5647-5656. |
| MLA | Liu, Xiaohao,et al."Highly efficient catalytic conversion of cellulose into acetol over Ni-Sn supported on nanosilica and the mechanism study".GREEN CHEMISTRY 21.20(2019):5647-5656. |
入库方式： OAI收割
来源：广州能源研究所
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