A novel catalyst with variable active sites for the direct hydrogenation of waste oils into jet fuel
文献类型：期刊论文
| 作者 | Li, Ming1,2,3,4; Fu, Junying1,2,3; Xing, Shiyou6; Yang, Lingmei1,2,3 ; Zhang, Xufeng1,2,3; Lv, Pengmei1,2,3,5; Wang, Zhongming1,2,3; Yuan, Zhenhong1,2,3
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| 刊名 | APPLIED CATALYSIS B-ENVIRONMENTAL
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| 出版日期 | 2020 |
| 卷号 | 260页码:14 |
| 关键词 | Lithium ion exchange Acid sites Metal centres ZSM-5 Jet fuel |
| ISSN号 | 0926-3373 |
| DOI | 10.1016/j.apcatb.2019.118114 |
| 通讯作者 | Lv, Pengmei(lvpm@ms.giec.ac.cn) |
| 英文摘要 | A series of novel NiO-LiZSM-5 catalysts with variable active sites was prepared to enhance the hydrogenation of waste oils into jet fuel components (C8-C16) by producing more olefins. In the early stage of the reaction, nickel oxide particles, as strong Lewis acid sites, promoted the cracking process of long-chain olefins into propylene and ethylene, which are the precursors of aromatics and iso-paraffins. As the reaction progressed, the nickel oxide was gradually reduced to nickel by H-2 in the system, and the strong Lewis acid sites were transformed into metal centres, which enhanced the hydrogenation performance of the catalyst. The jet fuel components converted from oleic acid by the catalyst could reach 80.42 mol%, which was approximately 10 mol% greater than that of the traditional Ni-ZSM-5 catalyst. Furthermore, four waste oils were efficiently converted into jet fuel by this catalytic system, the most effective content of jet fuel reached 91.7 mol%. |
| WOS关键词 | DIESEL-RANGE ALKANES ; BIODIESEL PRODUCTION ; FATTY-ACIDS ; OLEIC-ACID ; QUANTITATIVE CONVERSION ; SELECTIVE OXIDATION ; HYDROCARBON FUELS ; CARBON DEPOSITION ; PYROLYSIS OIL ; NONEDIBLE OIL |
| 资助项目 | Guangdong Special Support Program[2017TX04Z109] ; Natural Science Foundation of Guangdong Province[2016A030308004] ; Natural Science Foundation of Guangdong Province[2018A030310078] ; National Natural Science Foundation of China[21576260] ; National Natural Science Foundation of China Youth[51806225] ; National Natural Science Foundation of China Youth[51606201] ; Special Funds of Applied Science and Technology Research of Guangdong Province[2015B020241002] |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000496894300022 |
| 出版者 | ELSEVIER |
| 资助机构 | Guangdong Special Support Program ; Natural Science Foundation of Guangdong Province ; National Natural Science Foundation of China ; National Natural Science Foundation of China Youth ; Special Funds of Applied Science and Technology Research of Guangdong Province |
| 源URL | [http://ir.giec.ac.cn/handle/344007/26096]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Lv, Pengmei |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 5.Collaborat Innovat Ctr Biomass Energy, Zhengzhou 450002, Henan, Peoples R China 6.Univ Utrecht, Debye Inst Nanomat Sci, Inorgan Chem & Catalysis, Univ Weg 99, NL-3584 CG Utrecht, Netherlands |
| 推荐引用方式 GB/T 7714 | Li, Ming,Fu, Junying,Xing, Shiyou,et al. A novel catalyst with variable active sites for the direct hydrogenation of waste oils into jet fuel[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2020,260:14. |
| APA | Li, Ming.,Fu, Junying.,Xing, Shiyou.,Yang, Lingmei.,Zhang, Xufeng.,...&Yuan, Zhenhong.(2020).A novel catalyst with variable active sites for the direct hydrogenation of waste oils into jet fuel.APPLIED CATALYSIS B-ENVIRONMENTAL,260,14. |
| MLA | Li, Ming,et al."A novel catalyst with variable active sites for the direct hydrogenation of waste oils into jet fuel".APPLIED CATALYSIS B-ENVIRONMENTAL 260(2020):14. |
入库方式： OAI收割
来源：广州能源研究所
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