Molecular Structure and Formation Mechanism of Hydrochar from Hydrothermal Carbonization of Carbohydrates
文献类型：期刊论文
| 作者 | Shi, Ning1,2,3; Liu, Qiying2,3 ; He, Xiong1; Wang, Gui1; Chen, Ni1; Peng, Jiayu1; Ma, Longlong2,3
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| 刊名 | ENERGY & FUELS
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| 出版日期 | 2019-10-01 |
| 卷号 | 33期号:10页码:9904-9915 |
| ISSN号 | 0887-0624 |
| DOI | 10.1021/acs.energyfuels.9b02174 |
| 通讯作者 | Shi, Ning(shining@git.edu.cn) |
| 英文摘要 | Hydrochars are solid byproducts formed during the liquid-phase biorefinery process and could be used to generate functional carbonaceous materials, but the detailed molecular structure and the formation mechanism are still unclear. Herein, the formation of hydrochars from liquid-phase carbonization of biomass-derived compounds including glucose, fructose, xylose, ribose, dihydroxyacetone (DHA), 5-hydroxymethylfurfural (HMF), furfural (FF), and pyruvaldehyde (PRV) in water and inert polar organic solvents ethyl acetate (EAC) and tetrahydrofuran (THF) was studied. The carbohydrates were found to generate hydrochars in both water and the organic solvents, while the HMF and FF could generate hydrochars only in water. The a-carbonyl aldehydes, including PRV, 3-deoxyglucosone, and 2,5-dioxo-6-hydroxyhexanal (DHH), formed during the decomposition of carbohydrates were proposed to be the key primary precursors for hydrochar formation. The molecular structures of the hydrochars were characterized by elemental analysis, Fourier transform infrared analysis, and solid-state C-13 NMR analysis to confirm that the molecular formula of the hydrochars all could be approximately expressed as (C3H2O)(n), and the molecular structures of the hydrochars all consisted of polyaromatic hydrocarbon, phenolic, furanic, and aliphatic framents and a small amount of carbonyl/carboxyl groups. The presence of the polyaromatic hydrocarbon and phenolic fragments in the hydrochars suggested that aldol condensation played a critical role for hydrochar formation. By regarding the aldol condensation of alpha-carbonyl aldehydes as the initial step for hydrochar formation, we deduced the polymerization routes of these a-carbonyl aldehydes and found that the a-carbonyl aldehydes all could undergo aldol condensation followed by acetal cyclization and etherification to form polymers (C3H2O)(n) rich in furanic framework or undergo aldol condensation followed by a 1,2-hydride shift, intramolecular aldol condensation, and dehydration to generate polymers (C3H2O)(n) rich in the phenolic framework. One molecular structure containing polyaromatic hydrocarbon, phenolic, furanic, and aliphatic fragments is proposed for the hydrochars. |
| WOS关键词 | ACID-CATALYZED CONVERSION ; HIGH-YIELD PRODUCTION ; ETHYLENE-GLYCOL ; CARBON MATERIALS ; LEVULINIC ACID ; LACTIC-ACID ; CELLULOSE ; BIOMASS ; HUMINS ; GLUCOSE |
| 资助项目 | Academic New Seedling Plan Project of Guizhou Institute of Technology[Qjan Ke He [2017]5789-08] ; National Natural Science Foundation of China[51576199] ; Natural Science Foundation of Guangdong Province[2017A030308010] |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000492113000047 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | Academic New Seedling Plan Project of Guizhou Institute of Technology ; National Natural Science Foundation of China ; Natural Science Foundation of Guangdong Province |
| 源URL | [http://ir.giec.ac.cn/handle/344007/26190]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Shi, Ning |
| 作者单位 | 1.Guizhou Inst Technol, Sch Chem Engn, Guiyang 550003, Guizhou, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, Ning,Liu, Qiying,He, Xiong,et al. Molecular Structure and Formation Mechanism of Hydrochar from Hydrothermal Carbonization of Carbohydrates[J]. ENERGY & FUELS,2019,33(10):9904-9915. |
| APA | Shi, Ning.,Liu, Qiying.,He, Xiong.,Wang, Gui.,Chen, Ni.,...&Ma, Longlong.(2019).Molecular Structure and Formation Mechanism of Hydrochar from Hydrothermal Carbonization of Carbohydrates.ENERGY & FUELS,33(10),9904-9915. |
| MLA | Shi, Ning,et al."Molecular Structure and Formation Mechanism of Hydrochar from Hydrothermal Carbonization of Carbohydrates".ENERGY & FUELS 33.10(2019):9904-9915. |
入库方式： OAI收割
来源：广州能源研究所
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