High performance of Mo-promoted Ir/SiO2 catalysts combined with HZSM-5 toward the conversion of cellulose to C-5/C-6 alkanes
文献类型：期刊论文
| 作者 | Jin, Lele2,3; Li, Wenzhi2; Liu, Qiying3 ; Ma, Longlong2,3; Hu, Chao1; Ogunbiyi, Ajibola T.2; Wu, Mingwei2; Zhang, Qi2,3
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| 刊名 | BIORESOURCE TECHNOLOGY
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| 出版日期 | 2020-02-01 |
| 卷号 | 297页码:8 |
| 关键词 | Liquid fuel Microcrystalline cellulose Molybdenum Hydrogenolysis |
| ISSN号 | 0960-8524 |
| DOI | 10.1016/j.biortech.2019.122492 |
| 通讯作者 | Zhang, Qi(zhangqi@ms.giec.ac.cn) |
| 英文摘要 | In this study, the Mo-promoted Ir/SiO2 (Ir-MoOx/SiO2) catalysts combined with the zeolite HZSM-5 were used for the direct conversion of microcrystalline cellulose (MCC) to liquid fuel (C-5/C-6 alkanes) in n-dodecane/H2O system. A synergistic effect was formed between the partially reduced MoOx species and the Ir particles, which effectively promoted the catalytic activity of Ir/SiO2 catalyst. When the Mo/Ir molar ratio was 0.5, a high yield of C-5/C-6 alkanes (91.7%) was achieved at 210 degrees C for 12 h. In addition, the main component of C-5/C-6 alkanes was n-hexane, which was proven to be obtained by the hydrogenolysis of the key intermediate, sorbitol, formed from the hydrolysis and hydrogenation of MCC. |
| WOS关键词 | AQUEOUS-PHASE HYDROGENATION ; TETRAHYDROFURFURYL ALCOHOL ; SELECTIVE HYDROGENATION ; LEVULINIC ACID ; CORN STOVER ; ACETIC-ACID ; SORBITOL ; HYDROGENOLYSIS ; 1,5-PENTANEDIOL ; FUEL |
| 资助项目 | National Natural Science Foundation of China[51876209] ; National Key Research and Development Program of China[2018YFB1501402] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA 21060101] ; Natural Science Foundation of Guangdong Province[2017A030308010] |
| WOS研究方向 | Agriculture ; Biotechnology & Applied Microbiology ; Energy & Fuels |
| 语种 | 英语 |
| WOS记录号 | WOS:000504829800075 |
| 出版者 | ELSEVIER SCI LTD |
| 资助机构 | National Natural Science Foundation of China ; National Key Research and Development Program of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Natural Science Foundation of Guangdong Province |
| 源URL | [http://ir.giec.ac.cn/handle/344007/26226]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Zhang, Qi |
| 作者单位 | 1.Anhui Jianzhu Univ, Sch Environm & Energy Engn, Hefei 230601, Anhui, Peoples R China 2.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Lab Basic Res Biomass Convers & Utilizat, Hefei 230026, Anhui, Peoples R China 3.Chinese Acad Sci, CAS Key Lab Renewable Energy, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jin, Lele,Li, Wenzhi,Liu, Qiying,et al. High performance of Mo-promoted Ir/SiO2 catalysts combined with HZSM-5 toward the conversion of cellulose to C-5/C-6 alkanes[J]. BIORESOURCE TECHNOLOGY,2020,297:8. |
| APA | Jin, Lele.,Li, Wenzhi.,Liu, Qiying.,Ma, Longlong.,Hu, Chao.,...&Zhang, Qi.(2020).High performance of Mo-promoted Ir/SiO2 catalysts combined with HZSM-5 toward the conversion of cellulose to C-5/C-6 alkanes.BIORESOURCE TECHNOLOGY,297,8. |
| MLA | Jin, Lele,et al."High performance of Mo-promoted Ir/SiO2 catalysts combined with HZSM-5 toward the conversion of cellulose to C-5/C-6 alkanes".BIORESOURCE TECHNOLOGY 297(2020):8. |
入库方式： OAI收割
来源：广州能源研究所
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