Controlling Deoxygenation Pathways in Catalytic Fast Pyrolysis of Biomass and Its Components by Using Metal-Oxide Nanocomposites
文献类型:期刊论文
作者 | Zheng, Anqing1,2,3,4,5; Huang, Zhen2,4,5; Wei, Guoqiang2,4,5; Zhao, Kun2,4,5; Jiang, Liqun2,4,5; Zhao, Zengli2,4,5; Tian, Yuanyu1; Li, Haibin2,4,5 |
刊名 | ISCIENCE |
出版日期 | 2020-01-24 |
卷号 | 23期号:1页码:27 |
DOI | 10.1016/j.isci.2019.100814 |
通讯作者 | Zhao, Zengli(zhaozl@ms.giec.ac.cn) ; Tian, Yuanyu(tianyy1008@126.com) |
英文摘要 | Selectively breaking the C-O bonds within biomass during catalytic fast pyrolysis (CFP) is desired, but extremely challenging. Herein, we develop a series of metal-oxide nanocomposites composed of W, Mo, Zr, Ti, or Al. It is demonstrated that the nanocomposites of WO3-TiO2-Al2O3 exhibit the highest deoxygenation ability during CFP of lignin, which can compete with the commercial HZSM-5 catalyst. The nanocomposites can selectively cleave the C-O bonds within lignin-derived phenols to form aromatics by direct demethoxylation and subsequent dehydration. Moreover, the nanocomposites can also achieve the selective breaking of the C-O bonds within xylan and cellulose to form furans by dehydration. The Bronsted and Lewis acid sites on the nanocomposites can be responsible for the deoxygenation of lignin and polysaccharides, respectively. This study provides new insights for the rational design of multifunctional catalysts that are capable of simultaneously breaking the C-O bonds within lignin and polysaccharides. |
WOS关键词 | SOLID ACID CATALYSTS ; LIGNOCELLULOSIC BIOMASS ; AROMATIC-HYDROCARBONS ; BIO-OIL ; CHEMICAL-STRUCTURE ; FLUIDIZED-BED ; LIGNIN ; MECHANISM ; CELLULOSE ; CONVERSION |
资助项目 | National Key R&D Program of China[2017YFE0124200] ; National Natural Science Foundation of China[51776209] ; National Natural Science Foundation of China[51661145011] ; National Natural Science Foundation of China[21406227] ; Natural Science Foundation of Shenzhen[JCYJ20170818164006890] ; Science and Technology Planning Project of Guangdong Province[2015A020215024] ; Youth Innovation Promotion Association, CAS[2018383] ; Pearl River S&T Nova Program of Guangzhou[201806010061] |
WOS研究方向 | Science & Technology - Other Topics |
语种 | 英语 |
出版者 | CELL PRESS |
WOS记录号 | WOS:000508685200065 |
资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China ; Natural Science Foundation of Shenzhen ; Science and Technology Planning Project of Guangdong Province ; Youth Innovation Promotion Association, CAS ; Pearl River S&T Nova Program of Guangzhou |
源URL | [http://ir.giec.ac.cn/handle/344007/26352] |
专题 | 中国科学院广州能源研究所 |
通讯作者 | Zhao, Zengli; Tian, Yuanyu |
作者单位 | 1.China Univ Petr East China, State Key Lab Heavy Oil Proc, Qingdao 266580, Shandong, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 3.Shenzhen Huazhong Univ Sci & Technol, Res Inst, Shenzhen 523000, Peoples R China 4.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 5.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Peoples R China |
推荐引用方式 GB/T 7714 | Zheng, Anqing,Huang, Zhen,Wei, Guoqiang,et al. Controlling Deoxygenation Pathways in Catalytic Fast Pyrolysis of Biomass and Its Components by Using Metal-Oxide Nanocomposites[J]. ISCIENCE,2020,23(1):27. |
APA | Zheng, Anqing.,Huang, Zhen.,Wei, Guoqiang.,Zhao, Kun.,Jiang, Liqun.,...&Li, Haibin.(2020).Controlling Deoxygenation Pathways in Catalytic Fast Pyrolysis of Biomass and Its Components by Using Metal-Oxide Nanocomposites.ISCIENCE,23(1),27. |
MLA | Zheng, Anqing,et al."Controlling Deoxygenation Pathways in Catalytic Fast Pyrolysis of Biomass and Its Components by Using Metal-Oxide Nanocomposites".ISCIENCE 23.1(2020):27. |
入库方式: OAI收割
来源:广州能源研究所
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