High dispersed Ru/SiO2-ZrO2 catalyst prepared by polyol reduction method and its catalytic applications in the hydrodeoxygenation of phenolic compounds and pyrolysis lignin-oil
文献类型：期刊论文
| 作者 | Shu, Riyang1; Li, Rongxuan1; Lin, Biqin1; Luo, Bowen1; Tian, Zhipeng2 |
| 刊名 | FUEL
 |
| 出版日期 | 2020-04-01 |
| 卷号 | 265页码:8 |
| 关键词 | Lignin-oil HDO Polyol Ru/SiO2-ZrO2 High metal dispersion Phenolic compounds Hydrocarbon fuels |
| ISSN号 | 0016-2361 |
| DOI | 10.1016/j.fuel.2019.116962 |
| 通讯作者 | Tian, Zhipeng(tianzp@ms.giec.ac.cn) |
| 英文摘要 | Metal particle size and metal dispersion significantly influence the catalyst activity, and an efficient catalytic upgrade of bio-oil to high-quality liquid fuel is always difficult. Herein, a high dispersed Ru/SiO2-ZrO2 catalyst was prepared by polyol reduction method, which exhibited a high catalytic activity on hydrodeoxygenation (HDO) of the phenolic compounds and pyrolysis lignin-oil. As a model compound, guaiacol had a conversion of 99.9% and a cyclohexane selectivity of 96.7% at the temperature of 240 degrees C. This polyol Ru/SiO2-ZrO2 catalyst had a good recyclability in the guaiacol HDO. No significant decrease on the catalytic activity was presented after continuous 5 runs, and the conversion kept close to 100% and the selectivity of cyclohexane kept above 88%. Several common phenolic compounds also enabled to be turned into corresponding cycloalkanes efficiently. The high Ru dispersion and the large amount of strong acid sites in the polyol Ru/SiO2-ZrO2 are the main reasons for the good catalytic performances. The synergetic effects between high dispersed metal site and strong acid site lead to a promoted efficiency in the HDO process to form the cycloalkanes. This active catalyst was also applicable to the upgrade of pyrolysis lignin-oil. After reaction, the content of hydrocarbons in the lignin-oil increased from 16.2% to 86.1%, and guaiacols and other oxygenated compounds were almost disappeared. The upgraded lignin-oil has potential to be used as high-quality fuels directly. |
| WOS关键词 | BIO-OIL ; PHASE HYDRODEOXYGENATION ; LIGNOCELLULOSIC BIOMASS ; CONVERSION ; HYDROGEN ; HYDROCARBONS ; PERFORMANCE ; CHEMICALS ; CELLULOSE ; NANOWIRES |
| 资助项目 | National Natural Science Foundation of China[51736005] ; Guangdong Natural Science Foundation[2018A030310536] |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000508914300057 |
| 出版者 | ELSEVIER SCI LTD |
| 资助机构 | National Natural Science Foundation of China ; Guangdong Natural Science Foundation |
| 源URL | [http://ir.giec.ac.cn/handle/344007/26519]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Tian, Zhipeng |
| 作者单位 | 1.Guangdong Univ Technol, Sch Mat & Energy, Guangdong Prov Key Lab Funct Soft Condensed Matte, Guangzhou 510006, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shu, Riyang,Li, Rongxuan,Lin, Biqin,et al. High dispersed Ru/SiO2-ZrO2 catalyst prepared by polyol reduction method and its catalytic applications in the hydrodeoxygenation of phenolic compounds and pyrolysis lignin-oil[J]. FUEL,2020,265:8. |
| APA | Shu, Riyang,Li, Rongxuan,Lin, Biqin,Luo, Bowen,&Tian, Zhipeng.(2020).High dispersed Ru/SiO2-ZrO2 catalyst prepared by polyol reduction method and its catalytic applications in the hydrodeoxygenation of phenolic compounds and pyrolysis lignin-oil.FUEL,265,8. |
| MLA | Shu, Riyang,et al."High dispersed Ru/SiO2-ZrO2 catalyst prepared by polyol reduction method and its catalytic applications in the hydrodeoxygenation of phenolic compounds and pyrolysis lignin-oil".FUEL 265(2020):8. |
入库方式： OAI收割
来源：广州能源研究所
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