Efficient transfer hydrogenation of biomass derived furfural and levulinic acid via magnetic zirconium nanoparticles: Experimental and kinetic study
文献类型：期刊论文
| 作者 | Gu, Jing1,2,3; Zhang, Jun1,2,3; Wang, Yazhuo1,2,3 ; Li, Denian1,2,3; Huang, Hongyu1,2,3; Yuan, Haoran1,2,3; Chen, Yong1,2,3
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| 刊名 | INDUSTRIAL CROPS AND PRODUCTS
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| 出版日期 | 2020-03-01 |
| 卷号 | 145页码:11 |
| 关键词 | Magnetic zirconium nanoparticles Furfural Levulinic acid Furfuryl alcohol gamma-Valerolactone |
| ISSN号 | 0926-6690 |
| DOI | 10.1016/j.indcrop.2020.112133 |
| 通讯作者 | Yuan, Haoran(yuanhr@ms.giec.ac.cn) |
| 英文摘要 | A series of magnetic zirconium nanoparticles with varied Zr/Fe molar ratios were synthesized and developed as acid - base bifunctional catalysts in the catalytic transfer hydrogenation (CTH) of biomass-derived furfural (FFR) and levulinic acid (LA) using 2-propanol as both hydrogen donor and solvent. Zirconium constituents coated on nano-sized Fe3O4 endowed the catalysts with abundant acid-base sites, moderate surface areas (94.0-187.6 m(2)/g) and pore sizes (3.42-9.51 nm), thus giving nearly 100 % yields of furfuryl alcohol (FA) and gamma-valerolactone (GVL) after 2 h of reaction. Particularly, competitive activation energy (E-a) for the CTH of FFR into FA over Zr1Fe1-300 was as low as 50.9 kJ/mol. Moreover, the easily separable nanocatalyst Zr1Fe1-150 was also applicable to CTH of various allcyl levulinates into GVL in high efficiency and could be reused for multiple cycles without obvious loss of its catalytic performance in the transfer hydrogenation of LA. |
| WOS关键词 | CATALYTIC TRANSFER HYDROGENATION ; SELECTIVE TRANSFER HYDROGENATION ; LIQUID-PHASE HYDROGENATION ; PONNDORF-VERLEY REDUCTION ; RUTHENIUM-BASED CATALYSTS ; GAMMA-VALEROLACTONE ; ETHYL LEVULINATE ; BETA ZEOLITE ; ALCOHOL ; CONVERSION |
| 资助项目 | National Key R&D Program of China[2018YFC1901200] ; National Natural Science Foundation of China[51976222] ; National Natural Science Foundation of China[51976223] ; Natural Science Foundation of Guangdong Province, China[2018A030313856] ; Natural Science Foundation of Guangdong Province, China[2016A030313173] ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou)[GML2O19ZDO1O1] ; Science and Technology Planning Project of Guangzhou[201904010351] |
| WOS研究方向 | Agriculture |
| 语种 | 英语 |
| WOS记录号 | WOS:000518865400071 |
| 出版者 | ELSEVIER |
| 资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China ; Natural Science Foundation of Guangdong Province, China ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) ; Science and Technology Planning Project of Guangzhou |
| 源URL | [http://ir.giec.ac.cn/handle/344007/26580]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Yuan, Haoran |
| 作者单位 | 1.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gu, Jing,Zhang, Jun,Wang, Yazhuo,et al. Efficient transfer hydrogenation of biomass derived furfural and levulinic acid via magnetic zirconium nanoparticles: Experimental and kinetic study[J]. INDUSTRIAL CROPS AND PRODUCTS,2020,145:11. |
| APA | Gu, Jing.,Zhang, Jun.,Wang, Yazhuo.,Li, Denian.,Huang, Hongyu.,...&Chen, Yong.(2020).Efficient transfer hydrogenation of biomass derived furfural and levulinic acid via magnetic zirconium nanoparticles: Experimental and kinetic study.INDUSTRIAL CROPS AND PRODUCTS,145,11. |
| MLA | Gu, Jing,et al."Efficient transfer hydrogenation of biomass derived furfural and levulinic acid via magnetic zirconium nanoparticles: Experimental and kinetic study".INDUSTRIAL CROPS AND PRODUCTS 145(2020):11. |
入库方式： OAI收割
来源：广州能源研究所
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