The role of CuO modified La0.7Sr0.3FeO3 perovskite on intermediate-temperature partial oxidation of methane via chemical looping scheme
文献类型：期刊论文
| 作者 | Zhang, Rongjiang1,2,3,4; Cao, Yan2,3,4; Li, Haibin2,3,4 ; Zhao, Zengli2,3,4; Zhao, Kun2,3,4; Jiang, Liqun2,3,4
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| 刊名 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
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| 出版日期 | 2020-02-07 |
| 卷号 | 45期号:7页码:4073-4083 |
| 关键词 | Chemical-looping partial oxidation (CLPO) Methane Syngas Perovskite Copper oxide Oxygen carrier |
| ISSN号 | 0360-3199 |
| DOI | 10.1016/j.ijhydene.2019.12.082 |
| 通讯作者 | Zhao, Kun(zhaokun@ms.giec.ac.cn) ; Jiang, Liqun(lqjiang@ms.giec.ac.cn) |
| 英文摘要 | Synthesis gas production via chemical-looping partial oxidation (CLPO) of methane reduces operating cost and likely avoids carbon dioxide emissions. Previous studies exhibit La0.7-Sr0.3FeO3 (LSF) a good high-temperature oxygen carrier, but not being applicable in intermediate-temperature CLPO processes. This work proposes a CuO modified LSF (xCuO/LSF, x = 2,5,10,15) for enhancing the reactivity of oxygen carriers at relatively low temperatures. Characterization methods, including N-2 physisorption, ICP-OES, H-2-TPR, XRD and XPS, are implemented to determine properties of xCuO/LSF. Fixed-bed experiments determine the best candidate under 750 degrees C is 10CuO/LSF. The methane conversion rate of 10CuO/LSF is more than 3 times compared to that of unmodified LSF and the concentration of syngas increases by 375% with the H-2/CO molar ratio of about 2.5. The regenerability of 10CuO/LSF proves to be good. This study provides a promising and simple way to lower the operating temperature of the CLPO process, likely leading a considerable energy saving. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved. |
| WOS关键词 | SYNTHESIS GAS GENERATION ; OXYGEN CARRIERS ; HYDROGEN-PRODUCTION ; OXIDES ; REDOX ; FE ; REACTIVITY ; CONVERSION ; CHALLENGE ; SYNGAS |
| 资助项目 | National Key Research and Development Program of China[2017YFE0105500] ; National Natural Science Foundation of China[51876205] ; Pearl River S&T Nova Program of Guangzhou[201906010092] |
| WOS研究方向 | Chemistry ; Electrochemistry ; Energy & Fuels |
| 语种 | 英语 |
| WOS记录号 | WOS:000514018600021 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 资助机构 | National Key Research and Development Program of China ; National Natural Science Foundation of China ; Pearl River S&T Nova Program of Guangzhou |
| 源URL | [http://ir.giec.ac.cn/handle/344007/26618]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Zhao, Kun; Jiang, Liqun |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou, Peoples R China 3.CAS Key Lab Renewable Energy, Beijing, Peoples R China 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Rongjiang,Cao, Yan,Li, Haibin,et al. The role of CuO modified La0.7Sr0.3FeO3 perovskite on intermediate-temperature partial oxidation of methane via chemical looping scheme[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2020,45(7):4073-4083. |
| APA | Zhang, Rongjiang,Cao, Yan,Li, Haibin,Zhao, Zengli,Zhao, Kun,&Jiang, Liqun.(2020).The role of CuO modified La0.7Sr0.3FeO3 perovskite on intermediate-temperature partial oxidation of methane via chemical looping scheme.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,45(7),4073-4083. |
| MLA | Zhang, Rongjiang,et al."The role of CuO modified La0.7Sr0.3FeO3 perovskite on intermediate-temperature partial oxidation of methane via chemical looping scheme".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 45.7(2020):4073-4083. |
入库方式： OAI收割
来源：广州能源研究所
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