One-Pot Hydrogenation of Furfural into Tetrahydrofurfuryl Alcohol under Ambient Conditions over PtNi Alloy Catalyst
文献类型：期刊论文
| 作者 | Wu, Jingcheng1,2,3,4; Zhang, Xinghua2,3,4 ; Chen, Qiang1,2,3,4; Chen, Lungang2,3,4; Liu, Qiying2,3,4; Wang, Chenguang2,3,4; Ma, Longlong2,3,4
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| 刊名 | ENERGY & FUELS
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| 出版日期 | 2020-02-01 |
| 卷号 | 34期号:2页码:2178-2184 |
| ISSN号 | 0887-0624 |
| DOI | 10.1021/acs.energyfuels.9b02811 |
| 通讯作者 | Wang, Chenguang(wangcg@ms.giec.ac.cn) |
| 英文摘要 | Furfural (FAL), a promising renewable platform compound from biomass, can be totally hydrogenated to an industrially important platform chemical, tetrahydrofurfuryl alcohol (THFA). In this work, a high yield of THFA was obtained by one-pot hydrogenation of FAL over a PtNi catalyst under mild reaction conditions. Small PtNi alloy particles were well distributed on active carbon. The catalysts were characterized by several physical-chemical technologies (transmission electron microscopy, X-ray diffraction, energy-dispersive spectroscopy, and inductively coupled plasma spectroscopy). Temperature-programmed reduction with hydrogen and in situ X-ray photoelectron spectroscopy demonstrate the presence of PtNi alloy. The electron-rich metal Pt could facilitate the heterolytic dissociation of hydrogen and promote the hydrogenation of FAL. Pt sites on the surface facilitate the adsorption at aldehyde (C=O) groups, and the furan ring strongly adsorbs on the Ni surface. Low reaction temperature is advantageous to reduce side reactions. Various metal concentrations were employed in this reaction; Pt(3)Ni(3)/C catalyst exhibits the best performance, achieving 99% FAL conversion and 93% THFA yield at 35 degrees C and under 2 MPa H-2. |
| WOS关键词 | SELECTIVE HYDROGENATION ; PHASE HYDROGENATION ; CONVERSION ; BIOMASS ; REACTIVITY ; CELLULOSE ; ACID |
| 资助项目 | National Key R&D Program of China[2018YFB1501504] ; National Natural Science Foundation of China[51476175] ; National Natural Science Foundation of China[51536009] ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BTO1N092] ; CAS Pioneer Hundred Talents Plan |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000518215400108 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program ; CAS Pioneer Hundred Talents Plan |
| 源URL | [http://ir.giec.ac.cn/handle/344007/26621]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Wang, Chenguang |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 51640, Peoples R China 3.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 51640, Peoples R China 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 51640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Jingcheng,Zhang, Xinghua,Chen, Qiang,et al. One-Pot Hydrogenation of Furfural into Tetrahydrofurfuryl Alcohol under Ambient Conditions over PtNi Alloy Catalyst[J]. ENERGY & FUELS,2020,34(2):2178-2184. |
| APA | Wu, Jingcheng.,Zhang, Xinghua.,Chen, Qiang.,Chen, Lungang.,Liu, Qiying.,...&Ma, Longlong.(2020).One-Pot Hydrogenation of Furfural into Tetrahydrofurfuryl Alcohol under Ambient Conditions over PtNi Alloy Catalyst.ENERGY & FUELS,34(2),2178-2184. |
| MLA | Wu, Jingcheng,et al."One-Pot Hydrogenation of Furfural into Tetrahydrofurfuryl Alcohol under Ambient Conditions over PtNi Alloy Catalyst".ENERGY & FUELS 34.2(2020):2178-2184. |
入库方式： OAI收割
来源：广州能源研究所
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