Pomelo peel-derived, N-doped biochar microspheres as an efficient and durable metal-free ORR catalyst in microbial fuel cells
文献类型：期刊论文
| 作者 | Zhang, Yuyuan2,3; Deng, Lifang2; Hu, Huawen3; Qiao, Yu1; Yuan, Haoran2 ; Chen, Dongchu3; Chang, Menglei3; Wei, Hongyang3
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| 刊名 | SUSTAINABLE ENERGY & FUELS
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| 出版日期 | 2020-04-01 |
| 卷号 | 4期号:4页码:1642-1653 |
| ISSN号 | 2398-4902 |
| DOI | 10.1039/c9se00834a |
| 通讯作者 | Deng, Lifang(denglf@ms.giec.ac.cn) ; Hu, Huawen(huawenhu@126.com) |
| 英文摘要 | Microbial fuel cells (MFCs) are widely explored for promising green and renewable energy generation; however, their strong reliance on noble metal-based catalysts causes high fabrication costs and thus limits their widespread applications. Herein, metal-free alternatives derived from naturally abundant, renewable pomelo peels are explored. Two kinds of pomelo peel-derived novel N-doped carbocatalysts are presented, i.e., biochar microspheres (BCMs) and their activated porous counterpart (a-BCMs). In comparison with BCMs, the thermal activation processing endowed a-BCMs with significantly enhanced porosity, an elevated N doping content (2.41 vs. 0.51 at%), a 5-fold increased specific surface area (314.3 vs. 62.8 m(2) g(-1)), and a much improved electrical conductivity (0.13 vs. 0.006 S cm(-1)). This metal-free a-BCM catalyst is subsequently employed to construct an MFC cathode for the oxygen reduction reaction (ORR), and an impressive electrocatalytic activity is achieved in 0.1 mol L-1 phosphate-buffered saline (PBS) buffer. The maximum power density reaches as high as 907.2 mW m(-2), comparable to that of the costly Pt/C counterpart (1022.9 mW m(-2)). The long-term durability of the a-BCM electrocatalyst is also demonstrated by continuous running for 90 days, even superior to that of Pt/C. The origin of this excellent electrocatalytic performance of a-BCMs is deeply analyzed and discussed. Furthermore, the 4e(-) reduction pathway is also unraveled for the efficient and durable carbocatalysis of the ORR over a-BCMs in MFCs. |
| WOS关键词 | OXYGEN REDUCTION REACTION ; LONG-TERM PERFORMANCE ; AIR-CATHODE ; ACTIVATED CARBON ; POROUS CARBON ; FREE ELECTROCATALYSTS ; ANODE MODIFICATION ; NITROGEN ; GRAPHENE ; NANOPARTICLES |
| 资助项目 | National Natural Science Foundation of China[51702050] ; National Natural Science Foundation of China[51906045] ; Foundation of CAS Key Laboratory of Renewable Energy[Y807k61001] ; Foundation of State Key Laboratory of Coal Combustion[FSKLCCA1808] ; Open Research Foundation of Jiangsu Provincial Key Laboratory of Biomass Energy and Materials[JSBEM201608] ; Key Project of Department of Education of Guangdong Province[2016GCZX008] ; Featured Innovation Project of the Department of Education of Guangdong Province[2017KTSCX188] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000526855200054 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | National Natural Science Foundation of China ; Foundation of CAS Key Laboratory of Renewable Energy ; Foundation of State Key Laboratory of Coal Combustion ; Open Research Foundation of Jiangsu Provincial Key Laboratory of Biomass Energy and Materials ; Key Project of Department of Education of Guangdong Province ; Featured Innovation Project of the Department of Education of Guangdong Province |
| 源URL | [http://ir.giec.ac.cn/handle/344007/26980]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Deng, Lifang; Hu, Huawen |
| 作者单位 | 1.Huazhong Univ Sci & Technol, State Key Lab Coal Combust, Wuhan 430074, Hubei, Peoples R China 2.Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Foshan Univ, Sch Mat Sci & Energy Engn, Foshan 528000, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Yuyuan,Deng, Lifang,Hu, Huawen,et al. Pomelo peel-derived, N-doped biochar microspheres as an efficient and durable metal-free ORR catalyst in microbial fuel cells[J]. SUSTAINABLE ENERGY & FUELS,2020,4(4):1642-1653. |
| APA | Zhang, Yuyuan.,Deng, Lifang.,Hu, Huawen.,Qiao, Yu.,Yuan, Haoran.,...&Wei, Hongyang.(2020).Pomelo peel-derived, N-doped biochar microspheres as an efficient and durable metal-free ORR catalyst in microbial fuel cells.SUSTAINABLE ENERGY & FUELS,4(4),1642-1653. |
| MLA | Zhang, Yuyuan,et al."Pomelo peel-derived, N-doped biochar microspheres as an efficient and durable metal-free ORR catalyst in microbial fuel cells".SUSTAINABLE ENERGY & FUELS 4.4(2020):1642-1653. |
入库方式： OAI收割
来源：广州能源研究所
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