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Catalytic Production of Oxygenated and Hydrocarbon Chemicals From Cellulose Hydrogenolysis in Aqueous Phase

文献类型：期刊论文

作者Xin, Haosheng3,4,5,6; Hu, Xiaohong3,4,5,6; Cai, Chiliu4,5,6; Wang, Haiyong4,5,6; Zhu, Changhui3,4,5,6; Li, Song3,4,5,6; Xiu, Zhongxun2; Zhang, Xinghua4,5,6; Liu, Qiying1,4,5,6; Ma, Longlong4,5,6
刊名FRONTIERS IN CHEMISTRY
出版日期2020-05-05
卷号8页码:20
关键词cellulose hydrolysis hydrogenolysis biorefinery catalysis aqueous phase
ISSN号2296-2646
DOI10.3389/fchem.2020.00333
通讯作者Liu, Qiying(liuqy@ms.giec.ac.cn)
英文摘要As the most abundant polysaccharide in lignocellulosic biomass, a clean and renewable carbon resource, cellulose shows huge capacity and roused much attention on the methodologies of its conversion to downstream products, mainly including platform chemicals and fuel additives. Without appropriate treatments in the processes of cellulose decompose, there are some by-products that may not be chemically valuable or even truly harmful. Therefore, higher selectivity and more economical and greener processes would be favored and serve as criteria in a correlational study. Aqueous phase, an economically accessible and immensely potential reaction system, has been widely studied in the preparation of downstream products of cellulose. Accordingly, this mini-review aims at making a related summary about several conversion pathways of cellulose to target products in aqueous phase. Mainly, there are four categories about the conversion of cellulose to downstream products in the following: (i) cellulose hydrolysis hydrogenation to saccharides and sugar alcohols, like glucose, sorbitol, mannose, etc.; (ii) selective hydrogenolysis leads to the cleavage of the corresponding glucose C-C and C-O bond, like ethylene glycol (EG), 1,2-propylene glycol (PG), etc.; (iii) dehydration of fructose and further oxidation, like 5-hydroxymethylfurfural (HMF), 2,5-furandicarboxylic acid (FDCA), etc.; and (iv) production of liquid alkanes via hydrogenolysis and hydrodeoxygenation, like pentane, hexane, etc. The representative products were enumerated, and the mechanism and pathway of mentioned reaction are also summarized in a brief description. Ultimately, the remaining challenges and possible further research objects are proposed in perspective to provide researchers with a lucid research direction.
WOS关键词ONE-POT CONVERSION ; HOT COMPRESSED WATER ; ETHYLENE-GLYCOL ; BIMETALLIC CATALYSTS ; BIOMASS CONVERSION ; ZINC-CHLORIDE ; IONIC LIQUID ; LIGNOCELLULOSIC BIOMASS ; GLUCOSE ISOMERIZATION ; HIGH-TEMPERATURE
资助项目National Key R&D Program of China[2018YFB1501402] ; National Science Foundation of China[51976220] ; National Science Foundation of China[51576199] ; Natural Science Foundation of Guangdong Province[2017A030308010] ; DNL Cooperation Fund, CAS[DNL180302] ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences[XDA21060102]
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000536363500001
出版者FRONTIERS MEDIA SA
资助机构National Key R&D Program of China ; National Science Foundation of China ; Natural Science Foundation of Guangdong Province ; DNL Cooperation Fund, CAS ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences
源URL[http://ir.giec.ac.cn/handle/344007/27131]  
专题中国科学院广州能源研究所
通讯作者Liu, Qiying
作者单位1.Dalian Natl Lab Clean Energy, Dalian, Peoples R China
2.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou, Peoples R China
3.Univ Chinese Acad Sci, Beijing, Peoples R China
4.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou, Peoples R China
5.CAS Key Lab Renewable Energy, Guangzhou, Peoples R China
6.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou, Peoples R China
推荐引用方式
GB/T 7714		 Xin, Haosheng,Hu, Xiaohong,Cai, Chiliu,et al. Catalytic Production of Oxygenated and Hydrocarbon Chemicals From Cellulose Hydrogenolysis in Aqueous Phase[J]. FRONTIERS IN CHEMISTRY,2020,8:20.
APA Xin, Haosheng.,Hu, Xiaohong.,Cai, Chiliu.,Wang, Haiyong.,Zhu, Changhui.,...&Ma, Longlong.(2020).Catalytic Production of Oxygenated and Hydrocarbon Chemicals From Cellulose Hydrogenolysis in Aqueous Phase.FRONTIERS IN CHEMISTRY,8,20.
MLA Xin, Haosheng,et al."Catalytic Production of Oxygenated and Hydrocarbon Chemicals From Cellulose Hydrogenolysis in Aqueous Phase".FRONTIERS IN CHEMISTRY 8(2020):20.

入库方式： OAI收割

来源：广州能源研究所

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