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One-pot hydrodeoxygenation of biomass furan derivatives into decane under mild conditions over Pd/C combined with phosphotungstic acid

文献类型：期刊论文

作者Li, Song3,4,5,6; Yan, Long4,5,6; Liu, Qiying4,5,6; Liu, Jianguo4,5,6; Liu, Qiyu2; Fan, Wei2; Zhao, Xuelai1; Zhang, Xinghua4,5,6; Wang, Chenguang4,5,6; Ma, Longlong4,5,6
刊名GREEN CHEMISTRY
出版日期2020-05-07
卷号22期号:9页码:2889-2900
ISSN号1463-9262
DOI10.1039/d0gc00428f
通讯作者Yan, Long(yanlong@ms.giec.ac.cn) ; Zhang, Qi(zhangqi@ms.giec.ac.cn)
英文摘要One-pot hydrodeoxygenation (HDO) of biomass furan derivatives into long-chain alkanes remains unclear owing to the complicated reactions at high temperatures. Here, Pd/C combined with phosphotungstic acid (HPW), a strong Bronsted solid acid promoter, was developed to produce decane under mild conditions through the one-pot HDO of delta-furfurylidenelevulinic acid (FDLA). A 93.16% sum yield of alkanes including 89.53% yield of decane was obtained under 3 MPa H-2 at 170 degrees C for 4 h. The ring-opening and HDO of furans are accomplished at preheating stage, which enable to clarify the complicated reaction pathway. In addition, experimental validations and catalytic characterizations confirm that the synergistic effect of active acid-metal sites plays a critical role in the generation of alkanes via the formation and hydrogenolysis of lactone intermediates to aldehyde/alcohol. This work provides guidance for the one-pot HDO of biomass furan derivatives via the combination of metal catalyst and strong Bronsted solid acid under mild conditions.
WOS关键词FUEL RANGE ALKANES ; LEVULINIC ACID ; HETEROPOLY ACID ; BIFUNCTIONAL CATALYSTS ; LIQUID ALKANES ; CONVERSION ; CELLULOSE ; PLATFORM ; DIESEL ; DEOXYGENATION
资助项目National Key R&D Program of China[2017YFE0106600] ; National Natural Science Foundation of China[51876209] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA21060102] ; Natural Science Foundation of Guangdong Province[2017A030308010]
WOS研究方向Chemistry ; Science & Technology - Other Topics
语种英语
WOS记录号WOS:000533979200022
出版者ROYAL SOC CHEMISTRY
资助机构National Key R&D Program of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Natural Science Foundation of Guangdong Province
源URL[http://ir.giec.ac.cn/handle/344007/27134]  
专题中国科学院广州能源研究所
通讯作者Yan, Long; Zhang, Qi
作者单位1.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 233022, Peoples R China
2.Univ Massachusetts, Dept Chem Engn, 159 Goessman Lab,686 N Pleasant St, Amherst, MA 01003 USA
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China
5.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China
6.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
推荐引用方式
GB/T 7714		 Li, Song,Yan, Long,Liu, Qiying,et al. One-pot hydrodeoxygenation of biomass furan derivatives into decane under mild conditions over Pd/C combined with phosphotungstic acid[J]. GREEN CHEMISTRY,2020,22(9):2889-2900.
APA Li, Song.,Yan, Long.,Liu, Qiying.,Liu, Jianguo.,Liu, Qiyu.,...&Zhang, Qi.(2020).One-pot hydrodeoxygenation of biomass furan derivatives into decane under mild conditions over Pd/C combined with phosphotungstic acid.GREEN CHEMISTRY,22(9),2889-2900.
MLA Li, Song,et al."One-pot hydrodeoxygenation of biomass furan derivatives into decane under mild conditions over Pd/C combined with phosphotungstic acid".GREEN CHEMISTRY 22.9(2020):2889-2900.

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来源：广州能源研究所

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