Synthesis of Ordered Pt Nanocube Arrays Directed by Block Copolymer Nanotemplate and Their Potential on Ethanol Oxidation Reaction
文献类型：期刊论文
| 作者 | Wang, Zhi-da3; Gan, Yuan2,3; Mai, Yi-lang2,3; Shi, Yan3; Cao, Shuo1; Lu, Zhuo-xin3; Guo, Chang-qing3 ; Tan, Hongyi3; Yan, Chang-feng2,3
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| 刊名 | ANALYTICAL CHEMISTRY
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| 出版日期 | 2020-06-16 |
| 卷号 | 92期号:12页码:8046-8050 |
| ISSN号 | 0003-2700 |
| DOI | 10.1021/acs.analchem.0c01854 |
| 通讯作者 | Wang, Zhi-da(wangzd@ms.giec.ac.cn) ; Yan, Chang-feng(yancf@ms.giec.ac.cn) |
| 英文摘要 | In this work, well-ordered platinum (Pt) nanocubes (NCs), with precise control on the size and the spatial arrangement, are synthesized from a microemulsion overgrowth in a block copolymer (BC) nanotemplate. The nanovials on this self-assembled BC template serve as microreactors for the reduction of the HCl/H2PtCl6 precursor and direct the ordered periodic arrangement of the reduced Pt nanoparticles (NPs). As the content of HCl increases from 0% to 25%, the Pt NPs evolve from quasi-spheres to NCs, for which the density functional theory (DFT) computation reveals that the different adsorption energies of CI and HCl dominate this morphology transition. For their potential application in fuel cells, the electrochemical catalysis of the Pt NCs demonstrates a 2.8-fold mass activity in contrast to the commercial JM 40% catalyst at the same Pt loading in ethanol oxidation reaction (EOR) and a good stability of 2.2% ECSA loss over 10 000 CV cycling. |
| WOS关键词 | ELECTROCATALYSTS ; NANOPARTICLES |
| 资助项目 | DNL Cooperation Fund of CAS[DNL180405] ; Natural Science Foundation of Guangdong Province[2015A030312007] ; Natural Science Foundation of Guangdong Province[2017A030310539] ; Natural Science Foundation of Guangdong Province[2018A050506071] ; Guangzhou Science and Technology Project[201904010412] ; Guangzhou Science and Technology Project[202002030349] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000542222300011 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | DNL Cooperation Fund of CAS ; Natural Science Foundation of Guangdong Province ; Guangzhou Science and Technology Project |
| 源URL | [http://ir.giec.ac.cn/handle/344007/27346]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Wang, Zhi-da; Yan, Chang-feng |
| 作者单位 | 1.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Zhi-da,Gan, Yuan,Mai, Yi-lang,et al. Synthesis of Ordered Pt Nanocube Arrays Directed by Block Copolymer Nanotemplate and Their Potential on Ethanol Oxidation Reaction[J]. ANALYTICAL CHEMISTRY,2020,92(12):8046-8050. |
| APA | Wang, Zhi-da.,Gan, Yuan.,Mai, Yi-lang.,Shi, Yan.,Cao, Shuo.,...&Yan, Chang-feng.(2020).Synthesis of Ordered Pt Nanocube Arrays Directed by Block Copolymer Nanotemplate and Their Potential on Ethanol Oxidation Reaction.ANALYTICAL CHEMISTRY,92(12),8046-8050. |
| MLA | Wang, Zhi-da,et al."Synthesis of Ordered Pt Nanocube Arrays Directed by Block Copolymer Nanotemplate and Their Potential on Ethanol Oxidation Reaction".ANALYTICAL CHEMISTRY 92.12(2020):8046-8050. |
入库方式： OAI收割
来源：广州能源研究所
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