Amorphous FeNi-ZrO2-Catalyzed Hydrodeoxygenation of Lignin-Derived Phenolic Compounds to Naphthenic Fuel
文献类型：期刊论文
| 作者 | Chen, Qiang1,3; Cai, Chiliu3 ; Zhang, Xinghua2,3; Zhang, Qi3; Chen, Lungang3; Li, Yuping3; Wang, Chenguang3; Ma, Longlong3
|
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2020-06-29 |
| 卷号 | 8期号:25页码:9335-9345 |
| 关键词 | Amorphous FeNi-ZrO2 Guaiacol Lignin depolymerization product (LDP) Hydrodeoxygenation (HDO) Cycloalkanes |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.0c01457 |
| 通讯作者 | Zhang, Xinghua(zhangxh@ms.giec.ac.cn) |
| 英文摘要 | To obtain naphthenic fuel from lignin-derived phenolic compounds, an inexpensive amorphous catalyst FeNi-ZrO2 catalyst has been prepared by a cocrystallization method using the pristine Ni(NO3)(2), Fe(NO3)(3) and Zr(NO3)(4) as precursors. The catalyst was characterized systematically and tested by hydrodeoxygenation (HDO) using guaiacol as reactant. The results show that the amorphous FeNi-ZrO2 possesses an excellent texture structure and high catalytic activity. Guaiacol was completely converted with a yield of 98.5% hydrocarbons over the FeNi-ZrO2 catalyst with a content of 24 wt % Fe and 6 wt % Ni. It is found that iron is conducive to weaken the bond of C-O due to its oxygen affinity, promoting an improvement of the catalytic activity. Furthermore, lignin depolymerization products (LDP) were also converted to cycloalkanes with a yield of 48.39 wt %, suggesting that the amorphous FeNi-ZrO2 catalyst has a universal catalytic capacity in the HDO reaction of phenolic compounds. |
| WOS关键词 | GAS-PHASE HYDRODEOXYGENATION ; MODEL COMPOUNDS ; CATALYTIC HYDRODEOXYGENATION ; CARBON NANOTUBES ; PYROLYSIS OIL ; FE CATALYSTS ; HYDROGENATION ; GUAIACOL ; DEPOLYMERIZATION ; DECOMPOSITION |
| 资助项目 | National Natural Science Foundation of China[51876210] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA21060102] ; Tip-top Scientific and Technical Innovative Youth Talents of Guangdong Special Support Program[2019TQ05L238] ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01N092] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000545975600012 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Tip-top Scientific and Technical Innovative Youth Talents of Guangdong Special Support Program ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program |
| 源URL | [http://ir.giec.ac.cn/handle/344007/27426]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Zhang, Xinghua |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Qiang,Cai, Chiliu,Zhang, Xinghua,et al. Amorphous FeNi-ZrO2-Catalyzed Hydrodeoxygenation of Lignin-Derived Phenolic Compounds to Naphthenic Fuel[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2020,8(25):9335-9345. |
| APA | Chen, Qiang.,Cai, Chiliu.,Zhang, Xinghua.,Zhang, Qi.,Chen, Lungang.,...&Ma, Longlong.(2020).Amorphous FeNi-ZrO2-Catalyzed Hydrodeoxygenation of Lignin-Derived Phenolic Compounds to Naphthenic Fuel.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,8(25),9335-9345. |
| MLA | Chen, Qiang,et al."Amorphous FeNi-ZrO2-Catalyzed Hydrodeoxygenation of Lignin-Derived Phenolic Compounds to Naphthenic Fuel".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 8.25(2020):9335-9345. |
入库方式： OAI收割
来源：广州能源研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。