Encapsulation of Fe nanoparticles into an N-doped carbon nanotube/nanosheet integrated hierarchical architecture as an efficient and ultrastable electrocatalyst for the oxygen reduction reaction
文献类型：期刊论文
| 作者 | Li, Xiaoge4; Ni, Lu4; Zhou, Jinhua4; Xu, Lin3; Lu, Chunliang2; Yang, Gaixiu1 ; Ding, Weiping4; Hou, Wenhua4
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| 刊名 | NANOSCALE
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| 出版日期 | 2020-07-14 |
| 卷号 | 12期号:26页码:13987-13995 |
| ISSN号 | 2040-3364 |
| DOI | 10.1039/d0nr02618b |
| 通讯作者 | Xu, Lin(xulin001@njnu.edu.cn) ; Hou, Wenhua(whou@nju.edu.cn) |
| 英文摘要 | The exploration of cost-effective, highly efficient and robust electrocatalysts toward the oxygen reduction reaction (ORR) is of paramount significance for the advancement of future renewable energy conversion devices, and yet still remains a great challenge. Herein, we demonstrate a straightforward one-step pyrolysis strategy for the scalable synthesis of an iron-nitrogen-carbon hierarchically nanostructured catalyst, in which Fe-based nanoparticles are encapsulated in bamboo-like N-doped carbon nanotubesin siturooted from porous N-doped carbon nanosheets (Fe@N-C NT/NSs). The delicate fabrication of such an 0D/1D/2D integrated hierarchical architecture with encased Fe species and open configuration renders the formed Fe@N-C NT/NSs with sufficient confined active sites, reduced charge transfer resistance, improved diffusion kinetics and outstanding mechanical strength. As such, compared with commercial Pt/C, the optimized Fe@N-C NT/NSs catalyst exhibits efficient ORR activity, superior durability and strong tolerance to methanol in KOH medium. More impressively, when assembled as a cathode catalyst in a microbial fuel cell, the Fe@N-C NT/NSs electrode displays significantly enhanced power density and output voltage in comparison with commercial Pt/C, holding great promise in practical energy conversion devices. What's more, the simple yet reliable synthesis strategy developed here may shed light on the future design of advanced high-efficiency hierarchical architectures for diverse electrochemical applications and beyond. |
| WOS关键词 | FE/FE3C NANOPARTICLES ; CODOPED CARBON ; IRON ; NITROGEN ; CO ; CATALYSTS ; NANOCOMPOSITES ; NANOSTRUCTURE ; FRAMEWORKS ; NANOSHEETS |
| 资助项目 | Natural Science Foundation of China[21773116] ; Natural Science Foundation of China[21972068] ; Specialized Research Fund for the Doctoral Program of Higher Education (SRFDP)[20130091110010] ; Natural Science Foundation of Jiangsu Province[BK20171473] ; National Science Fund for Talent Training in Basic Science[J1103310] ; Modern Analysis Center of Nanjing University |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000547632900010 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | Natural Science Foundation of China ; Specialized Research Fund for the Doctoral Program of Higher Education (SRFDP) ; Natural Science Foundation of Jiangsu Province ; National Science Fund for Talent Training in Basic Science ; Modern Analysis Center of Nanjing University |
| 源URL | [http://ir.giec.ac.cn/handle/344007/27432]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Xu, Lin; Hou, Wenhua |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Yangzhou Univ, Analyt Testing Ctr, Yangzhou 225009, Jiangsu, Peoples R China 3.Nanjing Normal Univ, Sch Chem & Mat Sci, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Jiangsu Key Lab New Power Batteries, Nanjing 210023, Peoples R China 4.Nanjing Univ, Sch Chem & Chem Engn, Key Lab Mesoscop Chem MOE, Nanjing 210023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Xiaoge,Ni, Lu,Zhou, Jinhua,et al. Encapsulation of Fe nanoparticles into an N-doped carbon nanotube/nanosheet integrated hierarchical architecture as an efficient and ultrastable electrocatalyst for the oxygen reduction reaction[J]. NANOSCALE,2020,12(26):13987-13995. |
| APA | Li, Xiaoge.,Ni, Lu.,Zhou, Jinhua.,Xu, Lin.,Lu, Chunliang.,...&Hou, Wenhua.(2020).Encapsulation of Fe nanoparticles into an N-doped carbon nanotube/nanosheet integrated hierarchical architecture as an efficient and ultrastable electrocatalyst for the oxygen reduction reaction.NANOSCALE,12(26),13987-13995. |
| MLA | Li, Xiaoge,et al."Encapsulation of Fe nanoparticles into an N-doped carbon nanotube/nanosheet integrated hierarchical architecture as an efficient and ultrastable electrocatalyst for the oxygen reduction reaction".NANOSCALE 12.26(2020):13987-13995. |
入库方式： OAI收割
来源：广州能源研究所
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