Pyrolysis municipal sludge char supported Fe/Ni catalysts for catalytic reforming of tar model compound
文献类型：期刊论文
| 作者 | Wang, Shuxia1,2,3,4; shan, Rui1,2,3,4; Gu, Jing1,2,3,4; Zhang, Ju1,2,3,4; Yuan, Haoran1,2,3,4 ; Chen, Yong1,2,3,4
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| 刊名 | FUEL
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| 出版日期 | 2020-11-01 |
| 卷号 | 279页码:7 |
| 关键词 | Pyrolysis char Catalytic reforming Municipal sludge Syngas Tar conversion |
| ISSN号 | 0016-2361 |
| DOI | 10.1016/j.fuel.2020.118494 |
| 通讯作者 | Yuan, Haoran(yuanhr@ms.giec.ac.cn) |
| 英文摘要 | Pyrolytic char is widely used for tar removal due to its cost-effective and eco-friendly. In this work, the waste municipal sludge is selected to produce the composite catalyst with transition metal Fe/Ni, and the as-synthesized catalyst was used in the catalytic cracking of the tar model compound toluene by a laboratory-scale plant. The toluene conversion and the molar ratios of CO, H-2, CO2, CH4 and C2H4 in the generated gas were investigated. Results show that municipal sludge char-based catalysts are more likely to produce H-2-rich syngas (the molar ratio of syngas 75%), and the molar ratio of H-2 can reach 73.3% under optimal conditions. The FeNi bimetallic catalyst combines the advantages of different metal elements to make the catalyst performance more stable. Meanwhile, the effects of residence time (tau) and steam-to-carbon ratio (S/C) on the conversion rate were studied. As a result, the excessive residence time or steam-to-carbon ratio will have no more positive effect on the performance of the catalyst. Ultimately, the catalyst life test of 8 h was carried out, the results showed that cost-effective and green waste municipal sludge char-supported Fe/Ni catalysts in this work could be used for removal of the tar heavy component toluene. |
| WOS关键词 | BIOMASS GASIFICATION ; SYNGAS PRODUCTION ; RICE HUSK ; SOLID-WASTE ; BOTTOM ASH ; CRACKING ; PERFORMANCE ; CONVERSION ; CARBON ; DECOMPOSITION |
| 资助项目 | National Key R&D Program of China[2018YFC1901200] ; National Natural Science Foundation of China[51906248] ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory[GML2019ZD0101] ; Science and Technology Planning Project of Guangdong Province[2017B040404009] ; Guangdong Province Key Laboratory of Efficient and Clean Energy Utilization[2019ECEU02] ; key laboratory of renewable energy, Chinese Academy of Sciences[E029040101] |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000560044000010 |
| 出版者 | ELSEVIER SCI LTD |
| 资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory ; Science and Technology Planning Project of Guangdong Province ; Guangdong Province Key Laboratory of Efficient and Clean Energy Utilization ; key laboratory of renewable energy, Chinese Academy of Sciences |
| 源URL | [http://ir.giec.ac.cn/handle/344007/27600]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Yuan, Haoran |
| 作者单位 | 1.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 3.Southern Marine Sci & Engn Guangdong Lab, Guangzhou 511458, Peoples R China 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Shuxia,shan, Rui,Gu, Jing,et al. Pyrolysis municipal sludge char supported Fe/Ni catalysts for catalytic reforming of tar model compound[J]. FUEL,2020,279:7. |
| APA | Wang, Shuxia,shan, Rui,Gu, Jing,Zhang, Ju,Yuan, Haoran,&Chen, Yong.(2020).Pyrolysis municipal sludge char supported Fe/Ni catalysts for catalytic reforming of tar model compound.FUEL,279,7. |
| MLA | Wang, Shuxia,et al."Pyrolysis municipal sludge char supported Fe/Ni catalysts for catalytic reforming of tar model compound".FUEL 279(2020):7. |
入库方式： OAI收割
来源：广州能源研究所
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