The nonlinear optical properties of two-dimensional metal-organic framework
文献类型:期刊论文
作者 | Cheng, Xuemei2,3; Yao, Jingjing3; Zhang, Hui1; Wang, Xing2; Bai, Jintao3 |
刊名 | Journal of Alloys and Compounds |
出版日期 | 2021-02-25 |
卷号 | 855 |
ISSN号 | 09258388 |
关键词 | Two-dimensional metal-organic framework Spatial light modulation All-optical switch Nonlinear optics |
DOI | 10.1016/j.jallcom.2020.157433 |
产权排序 | 1 |
英文摘要 | We report the investigation on the nonlinear optical properties of two typical two-dimensional metal-organic frameworks (2D MOFs) - 2D Cu-MOF and Zn-MOF (copper/zinc 1,4-benzene dicarboxylate, CuBDC and ZnBDC) using spatial self-phase modulation (SSPM) and spatial cross-phase modulation (SXPM) methods. It is found that 2D Cu-MOF exhibits a large nonlinear optical coefficient n2=5.2010-11m2/Wandχ3=8.2410−11e.s.u. By contrast, no nonlinear optical effect was observed from 2D Zn-MOF under the same condition. The main reason is the Cu center of Cu-MOF has variable valence electrons and a vacant 3d atom orbit, which can form a conjugated system with organic ligands through the d-π interaction and therefore strengthen the nonlinear optical effect by the delocalization of π electrons. However, the Zn ion of Zn-MOF with fixed valence electrons and fully occupied d orbit makes it hard to produce observable nonlinear optical effect. Furthermore, we demonstrated the ability of 2D Cu-MOF in all-optical spatial light modulation and optical switch based on the principle of SXPM. This work sheds light on the physics of 2D MOFs in all-optical light modulation, providing an insight for rational design of 2D MOFs with high nonlinear optical coefficients in future. © 2020 Elsevier B.V. |
语种 | 英语 |
出版者 | Elsevier Ltd |
源URL | [http://ir.opt.ac.cn/handle/181661/93756] |
专题 | 西安光学精密机械研究所_瞬态光学技术国家重点实验室 |
通讯作者 | Cheng, Xuemei |
作者单位 | 1.Okinawa Institute of Science and Technology Graduate University, Okinawa; 9040495, Japan 2.State Key Laboratory of Transient Optics and Photonics, Chinese Academy of Sciences, Xi'an; 710119, China; 3.State Key Laboratory of Photoelectric Technology and Functional Materials, International Collaborative Center on Photoelectric Technology and Nano Functional Materials, Institute of Photonics & Photon-Technology, Northwest University, Xi'an; 710069, China; |
推荐引用方式 GB/T 7714 | Cheng, Xuemei,Yao, Jingjing,Zhang, Hui,et al. The nonlinear optical properties of two-dimensional metal-organic framework[J]. Journal of Alloys and Compounds,2021,855. |
APA | Cheng, Xuemei,Yao, Jingjing,Zhang, Hui,Wang, Xing,&Bai, Jintao.(2021).The nonlinear optical properties of two-dimensional metal-organic framework.Journal of Alloys and Compounds,855. |
MLA | Cheng, Xuemei,et al."The nonlinear optical properties of two-dimensional metal-organic framework".Journal of Alloys and Compounds 855(2021). |
入库方式: OAI收割
来源:西安光学精密机械研究所
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