Surface interaction of cadmium and zinc metal ions on Al(2)O(3)nanoparticles in aqueous solution
文献类型：期刊论文
| 作者 | Khan Shamshad1; Galstyan Hrachuhi1; Ahmed Bazai Nazir3; Idrees Muhammad2 |
| 刊名 | INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY
 |
| 出版日期 | 2020 |
| 页码 | DOI: 10.1080/03067319.2020.1796990 |
| 关键词 | Sorption ionic strength Al(2)o(3)nanoparticles thermodynamic parameters heavy metals |
| ISSN号 | 0306-7319 |
| DOI | 10.1080/03067319.2020.1796990 |
| 产权排序 | 1 |
| 通讯作者 | Khan, Shamshad(shamshadkhan768@yahoo.com) |
| 文献子类 | Article;Early Access |
| 英文摘要 | The adsorbent ability of Al(2)O(3)nanoparticles (ANPs) was examined to remove Cd(2+)and Zn(2+)from aqueous solution. The sorption of Cd(2+)and Zn(2+)on ANPs as a function of pH, ionic strength (IS), humic acid (HA), contact time, foreign ions and the temperature were investigated. It was observed that physico-chemical factors (pH and ionic strength) strongly affect the sorption of Cd(2+)and Zn(2+)on ANPs. Comparatively, the sorption of Cd(2+)and Zn(2+)dominated by surface complexation of the outer sphere at low pH values (pH < 8.0), while surface complexation of the inner sphere was the major sorption mechanism at elevated pH values (pH > 8.0). The maximum sorption capacity of Cd(2+)and Zn(2+)on ANPs calculated from the Langmuir model was 8.40 and 9.00 mg g(-1)respectively at 303 K, exhibiting higher efficiency for Zn(2+)sorption than Cd2+.The thermodynamic parameters ( increment H-0, increment S(0)and increment G(0)) showed that the adsorption of Cd(2+)and Zn(2+)was endothermic and spontaneous. This investigation exhibited that ANP is an efficient, inexpensive process and thereby reasonable technology for the elimination of metal ions from the contaminated aqueous source. |
| 电子版国际标准刊号 | 1029-0397 |
| WOS关键词 | TIO2 NANOPARTICLES ; AL2O3 NANOPARTICLES ; HUMIC-ACID ; CARBON NANOTUBES ; WATER-TREATMENT ; METHYLENE-BLUE ; HEAVY-METALS ; REMOVAL ; ADSORPTION ; KINETICS |
| 资助项目 | Scientific Research Project of Neijiang Normal University, China |
| WOS研究方向 | Chemistry ; Environmental Sciences & Ecology |
| 语种 | 英语 |
| WOS记录号 | WOS:000556069800001 |
| 出版者 | TAYLOR & FRANCIS LTD |
| 资助机构 | Scientific Research Project of Neijiang Normal University, China |
| 源URL | [http://ir.imde.ac.cn/handle/131551/35344]  |
| 专题 | 中国科学院水利部成都山地灾害与环境研究所 |
| 通讯作者 | Khan Shamshad |
| 作者单位 | 1.Neijiang Normal Univ, Sch Geog & Resources Sci, Neijiang, Peoples R China;;; 2.Neijiang Normal Univ, Sch Life Sci, Neijiang, Sichuan, Peoples R China 3.Chinese Acad Sci, Inst Mt Hazards & Environm, Key Lab Mt Hazards & Earth Surface Proc, Chengdu, Sichuan, Peoples R China;;; |
| 推荐引用方式 GB/T 7714 | Khan Shamshad,Galstyan Hrachuhi,Ahmed Bazai Nazir,et al. Surface interaction of cadmium and zinc metal ions on Al(2)O(3)nanoparticles in aqueous solution[J]. INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY,2020:DOI: 10.1080/03067319.2020.1796990. |
| APA | Khan Shamshad,Galstyan Hrachuhi,Ahmed Bazai Nazir,&Idrees Muhammad.(2020).Surface interaction of cadmium and zinc metal ions on Al(2)O(3)nanoparticles in aqueous solution.INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY,DOI: 10.1080/03067319.2020.1796990. |
| MLA | Khan Shamshad,et al."Surface interaction of cadmium and zinc metal ions on Al(2)O(3)nanoparticles in aqueous solution".INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY (2020):DOI: 10.1080/03067319.2020.1796990. |
入库方式： OAI收割
来源：成都山地灾害与环境研究所
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