中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Transport of 3,5,6-trichloro-2-pyrdionl (a main pesticide degradation product) in purple soil: Experimental and modeling

文献类型:会议论文

作者Lei Wenjuan1,2; Tang Xiangyu1; Zhou Xiangyang3
出版日期2018
会议日期AUG 14-20, 2016
会议地点Galway
关键词3,5,6-Trichloro-2-pyridinol Purple soil Transport Two-region model
卷号88
DOI10.1016/j.apgeochem.2017.07.010
页码179-187
国家IRELAND
英文摘要Purple soil, a loamy entisol dominating the hilly central Sichuan basin in the upper reaches of Yangtze River, is low in organic matter content and abundant in macropores that form the rapid transport network for water and solutes including pesticides. However, effects of soil's macroporosity on transport of pesticides has not been quantitatively explored and simulated at the column scale. In this study, we explore the transport of 3,5,6-trichloro-2-pyrdionl (TCP), a main pesticide degradation product, in purple soil through experiments and simulations on typical farmland categories, including rice-rape and vegetable farmland. Soil water retention characteristics (SWRCs) and physical properties are measured to learn the hydraulic parameters and porous structures of the soil. Batch experiments are conducted to obtain the adsorption coefficient of TCP on soil, and breakthrough curves of Br- (a conservative tracer) in undisturbed soil columns are applied to evaluate the hydrodynamics of TCP transport. The two-region model is used to simulate the transport processes, and the parameters are obtained by inversion simulation. It is found that TCP transport in purple soil exhibited complex patterns and is strongly affected by both chemical and physical non-equilibrium. A higher pollution risk on water body of rice-rape field is due to the stronger preferential flow and better pore connectivity despite the larger macroporosity observed in vegetable field. These results can provide useful data and modeling approach for evaluating the risk of pesticide leaching toward groundwater. (C) 2017 Elsevier Ltd. All rights reserved.
产权排序2
会议录APPLIED GEOCHEMISTRY
会议录出版者PERGAMON-ELSEVIER SCIENCE LTD
会议录出版地OXFORD
语种英语
ISSN号0883-2927
WOS记录号WOS:000424846900006
源URL[http://ir.imde.ac.cn/handle/131551/35215]  
专题成都山地灾害与环境研究所_山地表生过程与生态调控重点实验室
通讯作者Tang Xiangyu
作者单位1.Key Laboratory of Mountain Surface Processes and Ecological Regulation, Institute of Mountain Hazards and Environment, Chinese Academy of Sciences, Chengdu 610041, China;
2.College of Architecture & Environment, University of Sichuan, Chengdu 610065, China;
3.College of Water Resource & Hydropower, University of Sichuan, Chengdu 610065, China
推荐引用方式
GB/T 7714
Lei Wenjuan,Tang Xiangyu,Zhou Xiangyang. Transport of 3,5,6-trichloro-2-pyrdionl (a main pesticide degradation product) in purple soil: Experimental and modeling[C]. 见:. Galway. AUG 14-20, 2016.

入库方式: OAI收割

来源:成都山地灾害与环境研究所

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