Online Flow-Based Spectrophotometric Determination of Ferrous Iron Mass Fraction and Total Iron Mass Fraction in Twenty-Seven Rock Reference Materials Using a Schlenk line Technique
文献类型：期刊论文
| 作者 | Xue, Ding-Shuai1,3,4; Su, Ben-Xun1; Liu, Yan-Hong1; Zhang, Dan-Ping1; Guo, Qian1; Guo, Ju-Jie1; Sun, Jie-Fang2; Sakyi, Patrick Asamoah5 |
| 刊名 | GEOSTANDARDS AND GEOANALYTICAL RESEARCH
 |
| 出版日期 | 2020-09-10 |
| 页码 | 20 |
| ISSN号 | 1639-4488 |
| 关键词 | spectrophotometric flow-based Schlenk line ferrous iron total iron |
| DOI | 10.1111/ggr.12353 |
| 英文摘要 | We developed an online continuous-flow spectrophotometric method for determination of ferrous iron and total iron mass fractions in various types of geological certified reference materials (CRMs) using a Schlenk line technique to exclude oxygen during the digestion process. The continuous-flow technique enabled automatic, reliable and real-time analysis, and decreased sample and reagent consumption. The Schlenk line expels air to prevent oxidation during sample digestion. Compared with traditional spectrophotometric procedures, this analytical procedure is easier, more automated and more accurate. The composition of the acid matrix and time used to dissolve the samples were carefully examined. The procedure was tested on 186 replicates of twenty-seven rock CRMs, and the results showed good agreement with the compiled values from the literature. Based on the statistical data, the proposed procedure was found to be accurate within 0.12%m/mfor ferrous iron mass fraction and 0.084%m/mfor total iron mass fraction compared with the certified/recommended values. The proposed procedure is accurate, reproducible and has a high throughput (ten samples per hour). |
| WOS关键词 | ELEMENTAL CONCENTRATION DATA ; QUANTITATIVE ASSAY ; REFERENCE SAMPLES ; SILICATE ROCKS ; 1987 COMPILATION ; MINERALS ; FE(II) ; 1,10-PHENANTHROLINE ; SPECIATION ; COPPER(I) |
| 资助项目 | Equipment Function Development Technology Innovation Projects of the Chinese Academy of Sciences[IGG201704] ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences[T201804] ; National Natural Science Foundation of China[41403021] ; National Natural Science Foundation of China[41703021] ; National Natural Science Foundation of China[41525012] |
| WOS研究方向 | Geochemistry & Geophysics |
| 语种 | 英语 |
| 出版者 | WILEY |
| WOS记录号 | WOS:000567705700001 |
| 资助机构 | Equipment Function Development Technology Innovation Projects of the Chinese Academy of Sciences ; Equipment Function Development Technology Innovation Projects of the Chinese Academy of Sciences ; Equipment Function Development Technology Innovation Projects of the Chinese Academy of Sciences ; Equipment Function Development Technology Innovation Projects of the Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Equipment Function Development Technology Innovation Projects of the Chinese Academy of Sciences ; Equipment Function Development Technology Innovation Projects of the Chinese Academy of Sciences ; Equipment Function Development Technology Innovation Projects of the Chinese Academy of Sciences ; Equipment Function Development Technology Innovation Projects of the Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Equipment Function Development Technology Innovation Projects of the Chinese Academy of Sciences ; Equipment Function Development Technology Innovation Projects of the Chinese Academy of Sciences ; Equipment Function Development Technology Innovation Projects of the Chinese Academy of Sciences ; Equipment Function Development Technology Innovation Projects of the Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Equipment Function Development Technology Innovation Projects of the Chinese Academy of Sciences ; Equipment Function Development Technology Innovation Projects of the Chinese Academy of Sciences ; Equipment Function Development Technology Innovation Projects of the Chinese Academy of Sciences ; Equipment Function Development Technology Innovation Projects of the Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; Experimental Technology Innovation Fund of the Institute of Geology and Geophysics, Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China |
| 源URL | [http://ir.iggcas.ac.cn/handle/132A11/98227]  |
| 专题 | 地质与地球物理研究所_中国科学院矿产资源研究重点实验室 |
| 通讯作者 | Xue, Ding-Shuai; Su, Ben-Xun |
| 作者单位 | 1.Chinese Acad Sci, Inst Geol & Geophys, Key Lab Mineral Resources, Beijing 100029, Peoples R China 2.Beijing Ctr Dis Prevent & Control, Beijing Key Lab Diagnost & Traceabil Technol Food, Beijing 100013, Peoples R China 3.Chinese Acad Sci, Innovat Acad Earth Sci, Beijing 100029, Peoples R China 4.Univ Chinese Acad Sci, Coll Earth & Planetary Sci, Beijing, Peoples R China 5.Univ Ghana, Sch Phys & Math Sci, Dept Earth Sci, POB LG 58, Legon, Ghana |
| 推荐引用方式 GB/T 7714 | Xue, Ding-Shuai,Su, Ben-Xun,Liu, Yan-Hong,et al. Online Flow-Based Spectrophotometric Determination of Ferrous Iron Mass Fraction and Total Iron Mass Fraction in Twenty-Seven Rock Reference Materials Using a Schlenk line Technique[J]. GEOSTANDARDS AND GEOANALYTICAL RESEARCH,2020:20. |
| APA | Xue, Ding-Shuai.,Su, Ben-Xun.,Liu, Yan-Hong.,Zhang, Dan-Ping.,Guo, Qian.,...&Sakyi, Patrick Asamoah.(2020).Online Flow-Based Spectrophotometric Determination of Ferrous Iron Mass Fraction and Total Iron Mass Fraction in Twenty-Seven Rock Reference Materials Using a Schlenk line Technique.GEOSTANDARDS AND GEOANALYTICAL RESEARCH,20. |
| MLA | Xue, Ding-Shuai,et al."Online Flow-Based Spectrophotometric Determination of Ferrous Iron Mass Fraction and Total Iron Mass Fraction in Twenty-Seven Rock Reference Materials Using a Schlenk line Technique".GEOSTANDARDS AND GEOANALYTICAL RESEARCH (2020):20. |
入库方式： OAI收割
来源：地质与地球物理研究所
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